Rotational Isomerism in Fluorene Derivatives XIV Conformational Equilibria of 9-Substituted 9-(2-Cyanomethylphenyl) fluorene Derivatives

A. Nishida, S. Shirakawa, Toshinao Harada, S. Fujisaki, S. Kajigaeshi
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Abstract

(Eight 9-substituted 9-(2′-bromomethylphenyl)fluorene derivatives) (1) were prepared. Their conformational equilibria (ap\ightleftarrowssp) are discussed on the basis of kinetic data for internal rotation obtained by 1H NMR spectroscopy.
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芴衍生物的旋转异构十四。9-取代9-(2-氰甲基苯基)芴衍生物的构象平衡
制备了8个9-取代9-(2 ' -溴甲基苯基)芴衍生物。根据1H NMR内旋动力学数据讨论了它们的构象平衡(ap\ightleftarrowssp)。
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