Study on Preparation and Physical Properties of Fe2O3 Nanopowders

Yingming Shen, Jie Hu, Bianfang Zhang, X. Fang
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Abstract

Fe2O3 nanopowders were prepared by solid phase reaction method. The phase structure, microstructure, magnetic properties and gas sensor properties were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), vibration sample magnetometer (VSM) and gas sensor measuring system. It was found that the precursor sintered at 300 °C was spinel structure and transformed into α-Fe2O3 above 400 °C. The results of the room temperature hysteresis loops showed that the results obtained from the magnetic hystersis loop at room temperature were in agreement with those from the XRD spectra. Moreover, it was shown that γ-Fe2O3 can be used as gas sensor of the alcohol. he α-Fe2O3 nanopowders can be obtained at a lower sintering temperature. In addition, the gas sensor of γ-Fe2O3 was more sensitive to the alcohol.
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纳米Fe2O3粉体的制备及其物理性能研究
采用固相反应法制备了纳米Fe2O3粉体。采用x射线衍射(XRD)、扫描电镜(SEM)、振动样品磁强计(VSM)和气体传感器测量系统对材料的相结构、微观结构、磁性能和气敏性能进行了表征。发现在300℃烧结的前驱体为尖晶石结构,在400℃以上转变为α-Fe2O3。室温磁滞回线的结果表明,室温磁滞回线的结果与XRD谱图的结果吻合较好。结果表明,γ-Fe2O3可以作为乙醇的气体传感器。在较低的烧结温度下可以得到α-Fe2O3纳米粉体。此外,γ-Fe2O3气体传感器对醇的敏感度更高。
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