Obtaining conductive composites of PANI and thermoplastic polymers

Diana Nelly Contreras-Zarazúa, D. Contreras-López, R. Fuentes-Ramírez, Rosario Galindo-González
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Abstract

Currently, the polymers industry has gained increasing importance due to the versatility of its properties. In this work were synthesized copolymers of styrene with vinyl acetate at different concentrations through a process polymerization of suspension, which are the starting points for obtaining of composites with polyaniline synthesized PANI chemical oxidative polymerization process, used for doping HCl at a concentration of 1.5 M and ammonium persulfate 0.5 M in a mass radio of 1:1. The conductivity was evaluated by means of cyclic voltammetry and impedance spectroscopy, in order to determine the effect of the concentration of the polar monomer in the composite founded that increase concentration of polar comonomer the conductivity also too.
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制备聚苯胺与热塑性聚合物导电复合材料
目前,聚合物工业由于其特性的多功能性而变得越来越重要。本论文通过悬浮液的工艺聚合合成了不同浓度的苯乙烯与醋酸乙烯共聚物,这是用聚苯胺合成聚苯胺复合材料的化学氧化聚合工艺的起点,采用浓度为1.5 M的HCl和0.5 M的过硫酸铵以1:1的质量比掺杂。采用循环伏安法和阻抗谱法对复合材料的电导率进行了评价,以确定极性单体浓度对复合材料电导率的影响,发现极性单体浓度的增加对复合材料的电导率也有影响。
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