Thermo-reversibly cross-linked biomass-plastic acting rewritable shape memory

K. Inoue, M. Yamashiro, M. Iji
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Abstract

The article describes an intelligent biomass-plastic with a rewritable shape memory, which has advantages over petroleum-based plastics and will expand the use of biomass-plastics. A thermo-reversible bond between furan and maleimide was introduced into the molecular structure of polylactic acid (PLA). The bond acts like a thermo-switch, providing two normally incompatible characteristics, that is shape memory and recycling. When the thermo-switch is turned on at low temperature, the biomass-plastic acts complete shape memory. When the thermo-switch is turned off at high temperature for molding, the memory is easily erased, and the plastic becomes recyclable (i.e. rewritable)
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热可逆交联生物质塑料可重写形状记忆
本文描述了一种具有可重写形状记忆的智能生物质塑料,它比石油基塑料具有优势,将扩大生物质塑料的使用范围。在聚乳酸(PLA)的分子结构中引入了呋喃和马来酰亚胺之间的热可逆键。这种键就像一个热开关,提供了两个通常不相容的特性,即形状记忆和循环。当温度开关在低温下打开时,生物质塑料完成形状记忆。当热敏开关在高温下关闭进行成型时,记忆很容易被擦除,塑料变得可回收(即可重写)。
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