Properties of chrome coatings applied by various methods to zirconium alloy E110

A. A. Yakushkin, As “Src Rf Triniti”, V. Borisov, V. Trofimov
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Abstract

The issue presents the results of studies of methods for increasing the corrosion resistance of fuel claddings made from zirconium alloy E110, performed at the SRC RF TRINITI, using coatings (Al, Al2O3, Cr) by pulsed laser deposition, as well as magnetron sputtering and galvanic deposition of chromium. Also presented some results of studies of adhesion, microstructure and corrosion resistance of chromium coatings deposited by various methods. It was revealed that the corrosion resistance of the cladding of fuel rods with chrome coatings at temperatures of 1100 – 1200 °С practically does not depend on the method of their application. However, the coating method has a significant effect on their adhesion, with coatings obtained by atomic deposition methods and characterized by a continuous uniform structure have the greatest adhesion. The depth of oxidation of the outer surface of the cladding of a fuel rod when applying a chromium coating decreases by an average of 30 times for sponge-based alloy E110.
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不同镀铬方法对E110锆合金镀层性能的影响
这期报告介绍了在SRC RF TRINITI上使用脉冲激光沉积涂层(Al, Al2O3, Cr)以及磁控溅射和电沉积铬来提高由E110锆合金制成的燃料包层的耐腐蚀性的研究结果。并介绍了几种方法沉积铬镀层的附着力、显微组织和耐蚀性的研究结果。结果表明,在1100 ~ 1200°С温度范围内,镀铬燃料棒包层的耐蚀性能实际上与镀铬方法无关。然而,涂层方法对其附着力有显著影响,以原子沉积法获得的具有连续均匀结构的涂层具有最大的附着力。对于海绵基合金E110,镀铬后燃料棒包层外表面的氧化深度平均降低30倍。
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