The Influence of Diamagnetic Ions to Features of Crystalline and Magnetic Structures of BaFe11.9M0.1O19($\text{M}= \text{In}$ and Sc)

V. Turchenko, A. Doroshkevich, A. Trukhanov, S. Sumnikov, S. Trukhanov
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Abstract

The features of crystalline and magnetic structure of solid solution of barium ferrite BaFe11.9M0.1O19 (where M= In and Sc) with neutron diffraction method was studied. The substitution of Fe by In ions leads to increase of volume of unit cell while replacing with Sc ions insignificantly change the lattice parameters. The behavior of magnetic structure and unit cell parameters and atomic coordinates has been refined in a broad range of ambient temperature. The refinement of the magnetic structure was carried out within the framework of Gorter's model. The microstructural parameters of solid solutions BaFe12-xMxO19 (M= In and Sc) were determined by the high-resolution neutron diffraction method.
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抗磁性离子对BaFe11.9M0.1O19($\text{M}= \text{In}$ and Sc)晶体和磁性结构特征的影响
用中子衍射法研究了钡铁氧体BaFe11.9M0.1O19 (M= In和Sc)固溶体的晶体和磁性结构特征。In离子取代Fe离子使晶胞体积增大,而Sc离子取代Fe离子对晶格参数的影响不大。在较宽的环境温度范围内,磁性结构、单体胞参数和原子坐标的行为得到了细化。磁结构的细化是在Gorter模型的框架内进行的。采用高分辨中子衍射法测定了固溶体BaFe12-xMxO19 (M= In和Sc)的显微结构参数。
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