Mechanical Characterization Study of Additive as Nanofiller in Poly (ε-Caprolactone) Nanocomposite

Prarthana U. Dhanvijay
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Abstract

In order to keep with ever evolving technology in biomedical field, the demand for Poly (ε-caprolactone) (PCL) is gaining importance due to its biodegradability and biocompatibility. However, the low mechanical, barrier and thermal strength of PCL restricts its widespread use. These drawbacks of virgin PCL can be rectified by incorporating nanofiller into the PCL matrix. Till date, research has been carried out incorporating nano-fiber into PCL but to the best of our knowledge there is hardly any literature regarding organoclay modified nanofiller-PCL composites. The present study represents PCL nanocomposites preparation and characterization. The FTIR and XRD spectra observe uniform distribution of nanofiller in the PCL matrix. The characterization of mechanical properties shows enhancement in strength till 3.5 wt% loading and declining trend afterwards indicating agglomeration of nanofiller at higher wt% ratio. The increase in tensile strength without sacrificing elongation at break provides these composites with very attractive mechanical properties.
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聚(ε-己内酯)纳米复合材料中添加剂作为纳米填料的力学特性研究
随着生物医学领域技术的不断发展,聚ε-己内酯(PCL)的生物可降解性和生物相容性越来越受到人们的重视。但PCL的机械强度、阻隔强度和热强度较低,限制了其广泛应用。通过将纳米填料掺入PCL基体中,可以纠正原生PCL的这些缺点。迄今为止,已经进行了将纳米纤维掺入PCL的研究,但据我们所知,几乎没有关于有机粘土改性纳米填料-PCL复合材料的文献。本文研究了聚乳酸纳米复合材料的制备和表征。FTIR和XRD光谱观察到纳米填料在PCL基体中的均匀分布。力学性能表征表明,在3.5 wt%的载荷下,纳米填料的强度有所提高,在更高wt%的载荷下,强度呈下降趋势。在不牺牲断裂伸长率的情况下增加抗拉强度,使这些复合材料具有非常有吸引力的机械性能。
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