Modeling the Rejection Performance of Hollow Fiber Nanofiltration Membranes Modified by Negatively Charged-Modifying Macromolecule

N. Bolong, A. Ismail, M. Salim, D. Rana, T. Matsuura
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引用次数: 1

Abstract

Hollow fiber membranes using Polyethersulfone (PES) were fabricated in-house using phase inversion technique by modification with synthesized charged-surface modifying macromolecules (cSMM). The cSMM comprise with end-group component of Hydroxybenzene sulfonate or Hydroxybenzene carboxylate. The electrical properties of the membranes were modeled by utilizing the combination of irreversible thermodynamic model, Steric-Hindrance Pore (SHP) model and Teorell-Meyer-Sievers (TMS) model. The negatively-charged of the modified hollow fiber membranes was calculated based on sodium chloride rejection performance. The analysis of the modeling results revealed that sulfonate induce negative 1.61 electrical properties compared to carboxylate that is negative 1.49 for the modified PES membranes.
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负电荷修饰大分子修饰中空纤维纳滤膜截留性能的模拟
采用合成的带电表面修饰大分子(cSMM)对聚醚砜(PES)中空纤维进行相变改性,制备了中空纤维膜。cSMM由羟基磺酸盐或羟基羧酸盐端基组分组成。采用不可逆热力学模型、空间位阻孔(SHP)模型和Teorell-Meyer-Sievers (TMS)模型对膜的电学性质进行了综合建模。根据氯化钠截留性能计算了改性中空纤维膜的负电荷。建模结果分析显示,与羧酸盐相比,磺酸盐对改性PES膜的电性能为负1.61,羧酸盐为负1.49。
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