STUDY OF THE RHEOLOGICAL PROPERTIES OF COMPOSITE POLYMER STABILIZERS FOR DRILLING FLUIDS

Z. Artykova, О.К. Beysenbayev, S. Sakibayeva, К.S. Nadirov
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Abstract

This article presents the results of experimental data on the preparation of a composite heatresistant reagent for drilling fluids, including a modified copolymer based on polyacrylonitrile (by hydrolysis in the absence of a mixture of sodium hydroxide) and vinylsulfonic acid. A thermally stable composite reagent to polyvalent cations has been obtained, which reduces filtration and improves the anti-wear properties of clay suspensions. The values of the optimal reaction time and temperature were determined, the viscosity of the sampled polymer solutions was determined. The ratio of monomers and modification conditions are selected, this ensures a high conversion of monomers, and also increases the yield of the final product. The synthesized polymer of acrylonitrile and in the presence of fatty acids of gossypol resin and sulfuric acid in the pH = 3.5-5.5, with subsequent modification. The synthesized water-soluble polymer has a diphilic structure throughout the structure, the macromolecules of which contain a hydrophobic group and a hydrophilic part. They are able to adsorb and lower the interfacial free energy, which allows them to be classified as high-molecular surfactants.
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复合聚合物钻井液稳定剂的流变性能研究
本文介绍了制备一种钻井液复合耐热试剂的实验数据结果,包括一种基于聚丙烯腈(在没有氢氧化钠混合物的情况下通过水解)和乙烯基磺酸的改性共聚物。制备了一种热稳定的多价阳离子复合剂,减少了粘土悬浮液的过滤,提高了其抗磨性能。确定了最佳反应时间和温度,测定了所得聚合物溶液的粘度。通过对单体配比和改性条件的选择,既保证了单体的高转化率,又提高了最终产品的收率。在pH = 3.5-5.5的条件下,合成丙烯腈聚合物并在棉酚树脂和硫酸的脂肪酸存在下,进行后续改性。所合成的水溶性聚合物在整个结构中具有二亲性结构,其大分子中含有疏水基团和亲水部分。它们能够吸附并降低界面自由能,这使得它们可以被归类为高分子表面活性剂。
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