Cu-Al Intermetallic Growth Behaviour Study Under High Temperature Thermal Aging

C.L Cha, H.J Chong, HG Yaw, M. Chong, C. Tea
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引用次数: 1

Abstract

Copper (Cu) wire always gains the population in semiconductor industry for its superior thermal and electrical performance with increase of gold wire price in the market. The expanding use of electronics components in automotive electronics and rising in high reliability requirement are stimulating vigorous research and development on intermetallic (IMC) growth at the interface between Cu wire bonded ball and Aluminum (Al) bond pad metallization. In microelectronics packaging, IMC is an essential for interconnect formation between bonding wire and bond pad metallization. It grows during other assembly processes. Cu-Al intermetallic grows slowly and perceived higher reliability performance compare to Au-Al system especially during high temperature storage stress test. However, Cu wire with Al pad metallization formed type of IMC with no or very narrow range of solubility and this type of compound is very strong but very brittle. This study evaluates bare Cu wire bonding on Al pad metallization. As Cu wire IMC is known hardly observed at T0 after wire bonded, evaluation samples were subject to thermal aging to promote the IMC growth in un-molded strip form. Preliminary responses e.g wire pull, ball shear strength were collected. IMC coverage were analyzed and its growth thickness were examined from cross section sample by scanning electron microscopy (SEM) method. The stability of Cu-Al IMC in molded package form was studied under different high temperature storage stress test condition include both 150°C@2000hrs and 175°C@1000hrs. SEM based analysis technique - energy dispersive x-ray spectroscopy (EDX) is used to identify the IMC phases. Aside, transmission electron microscopy (TEM) analysis is adopted to understand IMC growth behavior and phase in depth. IMC thermal driven degradation mechanism was analyzed and discussed. (literature study, bench mark other study)
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高温热时效下Cu-Al金属间化合物生长行为研究
随着铜线市场价格的不断上涨,铜线以其优越的热学性能和电学性能一直受到半导体行业的青睐。随着电子元件在汽车电子领域应用的不断扩大和对可靠性要求的不断提高,对铜丝键合球与铝键合垫金属化界面金属间化合物(IMC)的研究和发展具有重要意义。在微电子封装中,IMC对于键合线和键合垫金属化之间的互连形成是必不可少的。它在其他组装过程中生长。与Au-Al体系相比,Cu-Al金属间化合物生长缓慢,具有更高的可靠性性能,特别是在高温储存应力测试中。然而,铜丝与Al垫金属化形成的IMC类型没有溶解度或溶解度范围很窄,这种类型的化合物很强但很脆。本研究评价了裸铜线在Al焊盘金属化上的结合。由于铜丝粘结后在T0时几乎观察不到IMC,因此对评价样品进行热时效以促进IMC以非模压带状形式生长。收集了初步响应如拉丝强度、球抗剪强度等。采用扫描电子显微镜(SEM)对样品的横截面进行了IMC覆盖分析和生长厚度测定。研究了Cu-Al IMC在150°C@2000hrs和175°C@1000hrs高温贮存应力条件下的模制封装稳定性。利用基于扫描电子显微镜的分析技术-能量色散x射线光谱(EDX)来鉴定IMC相。此外,采用透射电镜(TEM)分析,深入了解IMC的生长行为和相。分析并讨论了IMC热驱动降解机理。(文献研究,基准其他研究)
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