Hardening Properties of Foamed Concrete with Circulating Fluidized Bed Boiler Ash, Blast Furnace Slag, and Desulfurization Gypsum as the Binder

S. Na, Woong-Geol Lee, M. Song
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Abstract

Recently, a large amount of circulating fluidized bed boiler ash (CFBA) and desulfurization gypsum (DSG) has been produced, and it is essential to develop technology to utilize them. These materials have CaO and SO3, which are considered to be a stimulant for blast furnace slag (BFS). This study presents an experimental investigation of the compressive strength and heavy metal ions immobilization properties of cement-free materials comprising CFBA, BFS, and DSG. The feasibility of manufacturing foamed concrete using these materials was examined, and field test of foamed concrete was conducted. Experimentally, the flow, compressive strength, and heavy metal ions concentration were evaluated via inductively coupled plasma atomic emission spectroscopy (ICP-AES) of the paste and foamed concrete. The experimental investigation revealed the self-healing hardening ability of fluidized bed boiler ash. In addition, the compressive strength was increased with the increasing replacement rates of BFS and DSG in the CFBA paste, and the compressive strength of 14.6 - 17.2 MPa was recorded over 28 days of curing. From the result obtained, the feasibility of manufacturing foamed concrete with a foam volume of 120 L, incorporating the aforementioned materials, is confirmed. It was also found that after 28 days of age, a 7.9-MPa compressive strength of the foamed concrete was attained, and heavy metal ions elution in this foamed concrete was also significantly reduced. Therefore, CFBA, BFS, and DSG could be used as a binder for the foamed concrete.
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以循环流化床锅炉灰、高炉炉渣、脱硫石膏为粘结剂的泡沫混凝土的硬化性能
近年来,循环流化床锅炉产生了大量的锅炉灰(CFBA)和脱硫石膏(DSG),其利用技术的开发势在必行。这些材料含有CaO和SO3,它们被认为是高炉渣(BFS)的刺激物。本研究对含CFBA、BFS和DSG的无水泥材料的抗压强度和重金属离子固定化性能进行了实验研究。考察了用这些材料制备泡沫混凝土的可行性,并进行了泡沫混凝土的现场试验。实验中,通过电感耦合等离子体原子发射光谱(ICP-AES)对膏体和泡沫混凝土的流动、抗压强度和重金属离子浓度进行了评估。实验研究揭示了流化床锅炉灰的自愈硬化能力。此外,随着BFS和DSG在CFBA膏体中的替代率的增加,其抗压强度也有所提高,养护28 d后的抗压强度为14.6 ~ 17.2 MPa。结果表明,采用上述材料制备泡沫体积为120 L的泡沫混凝土是可行的。试验还发现,龄期28天后,泡沫混凝土抗压强度达到7.9 mpa,重金属离子的析出也明显减少。因此,CFBA、BFS和DSG均可作为泡沫混凝土的粘结剂。
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