ZEOLITE-BEARING AMYGDALOIDAL VOLCANIC AND VOLCANOCLASTIC ROCKS AT GABAL KATHERINE AREA, SOUTHERN SINAI, EGYPT

Imbarak, S. Hassan, R. Ahmad
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Abstract

The Gabal (G) Katherina complex in the southern Sinai of Egypt (Being a part of the ArabianShield) consisting mainly of volcanic arc granitoids, epiclastics and pyroclastic volcanic rocks (Rutiq volcanics), followed latterly by the emplacement of high-level intrusions (Katherina ring dyke) and calc-alkaline to slightly alkaline granites. The later-phase intrusions into the country rocks produced deferent degrees of contact aureole with significant alteration effects especially on the early-formed intermediate pyroclastics with their amygdules lava flows producing different degrees of zeolitization in the pyroclastic rocks, were investigated using Optical Microscopy, Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and wet chemical analyses. The studied volcanic rocks fall considerably in the basaltic andesite and rhyodacitedacite fields and show subcalcalkaline to calcalkaline affinities. On the other hand, the amygdaloidal volcanic rocks show low-temperature hydrothermal alteration characterized by the abundance of chloritization. Geochemically; Hf, Ta, Sr, Y, and Nb show slightly enrichment relative to the other zeolite-rich samples suggesting partial releasing of immobile elements from the volcanic rock during the alteration processes. Furthermore, zeolites found to fill the cavities in a non-uniform behavior. The subclass minerals such as phillipsite and chabazite have been accompanied by palagonite clasts, smectite, and calcite. Zeolites also occur in fibrous aggregates, partly or completely filling spheroid, ellipsoidal or irregular amygdules.
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埃及西奈半岛南部gabal Katherine地区含沸石杏仁状火山岩和火山碎屑岩
埃及西奈半岛南部的Gabal (G) Katherina杂岩(为阿拉伯地盾的一部分)主要由火山弧花岗岩、塑料和火山碎屑火山岩(Rutiq火山岩)组成,其后是高位侵入岩(Katherina环岩脉)和钙碱性至微碱性花岗岩。采用光学显微镜、扫描电镜(SEM)、x射线衍射(XRD)和湿化学分析等方法研究了后期侵入岩体产生不同程度的接触光晕,并具有明显的蚀变作用,特别是早期形成的中间火山碎屑及其淀粉状熔岩流在火山碎屑岩中产生不同程度的沸石化。研究的火山岩主要落在玄武岩安山岩和流纹酸玄武岩田中,表现出亚钙碱性和钙碱性亲和关系。另一方面,杏仁状火山岩表现为低温热液蚀变,其特征为丰富的绿泥化。地球化学;Hf、Ta、Sr、Y和Nb相对于其他富沸石样品略有富集,说明在蚀变过程中,部分固定元素从火山岩中释放出来。此外,发现沸石以不均匀的行为填充空腔。亚类矿物如菲利石和茶辉石伴随有古长石碎屑、蒙脱石和方解石。沸石也以纤维聚集体形式存在,部分或完全填充球形、椭球状或不规则的杏仁核。
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