Quantitative incorporation of sodium in CuInSe/sub 2/ and Cu(In,Ga)Se/sub 2/ photovoltaic devices

J. Granata, J. Sites, S. Asher, R. Matson
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引用次数: 18

Abstract

Sodium was deliberately introduced into CuInSe/sub 2/ and Cu(In,Ga)Se/sub 2/ photovoltaic solar cells in a controlled manner. The amount of sodium added was varied in order to pinpoint the range of sodium concentrations in the CuIn(Ga)Se/sub 2/ film for optimal performance. Films were analyzed using secondary ion mass spectroscopy and induced-coupling plasma spectroscopy to quantify the sodium concentration. The results are compared with the calculation. Finished devices show improvements in open-circuit voltage, fill factor and hole density for sodium concentrations in the range of approximately 0.05 to 0.5 atomic percent.
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CuInSe/sub 2/和Cu(in,Ga)Se/sub 2/光伏器件中钠的定量掺入
将钠可控地引入到Cu(In,Ga)Se/sub 2/和Cu(In,Ga)Se/sub 2/光伏太阳能电池中。为了确定CuIn(Ga)Se/sub - 2/薄膜中钠的浓度范围以获得最佳性能,研究了不同钠的添加量。利用二次离子质谱和诱导耦合等离子体谱对膜进行分析,定量测定钠浓度。结果与计算结果进行了比较。成品器件在钠浓度约为0.05至0.5个原子百分比范围内显示出开路电压、填充因子和空穴密度的改善。
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