Effect of pH on Structure and Green Emission of Er/Yb/Mo Tri-doped Hydroxyapatite

H. N. Van, N. Dung, N. Hải, Cu Van Thai, V. T. N. Minh, N. Truong, B. Hoan, P. Huan, P. H. Vuong
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Abstract

This paper reported the impact of pH on the structure, morphology, and the green upconversion (UC) emission of Er/Yb/Mo tri-doped hydroxyapatite (HA) synthesized through hydrothermal method. X-ray diffraction confirmed that the pH of the solution strongly influenced the phase composition of the phosphors, and HA single phase was obtained at a high pH value. Transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) images of the phosphor exhibited rod-like morphology, and their length increased with increased of the pH values. Under laser-diode excitation wavelength of 975 nm, the phosphor showed typical upconversion emission bands of the  ion: strong green emission bands around 510-535/540-560 nm and weak red emission bands around 630-680 nm. The green and red emission intensity as a function of pH reached its maximum value at pH8. Finally, the emission intensity of
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pH对Er/Yb/Mo三掺杂羟基磷灰石结构和绿色发光的影响
本文报道了pH对水热法合成的Er/Yb/Mo三掺杂羟基磷灰石(HA)的结构、形态和绿色上转换(UC)发射的影响。x射线衍射证实,溶液的pH值对荧光粉的相组成有强烈的影响,在高pH值下获得了HA单相。透射电子显微镜(TEM)和高分辨率透射电子显微镜(HRTEM)图像显示荧光粉呈棒状,其长度随pH值的增加而增加。在激光二极管激发波长为975 nm时,荧光粉表现出典型的离子上转换发射带:510 ~ 535/540 ~ 560nm附近的强绿色发射带和630 ~ 680 nm附近的弱红色发射带。绿色和红色发射强度随pH值的变化在pH8时达到最大值。的发射强度
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