H. N. Van, N. Dung, N. Hải, Cu Van Thai, V. T. N. Minh, N. Truong, B. Hoan, P. Huan, P. H. Vuong
{"title":"Effect of pH on Structure and Green Emission of Er/Yb/Mo Tri-doped Hydroxyapatite","authors":"H. N. Van, N. Dung, N. Hải, Cu Van Thai, V. T. N. Minh, N. Truong, B. Hoan, P. Huan, P. H. Vuong","doi":"10.25073/2588-1124/vnumap.4680","DOIUrl":null,"url":null,"abstract":"This paper reported the impact of pH on the structure, morphology, and the green upconversion (UC) emission of Er/Yb/Mo tri-doped hydroxyapatite (HA) synthesized through hydrothermal method. X-ray diffraction confirmed that the pH of the solution strongly influenced the phase composition of the phosphors, and HA single phase was obtained at a high pH value. Transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) images of the phosphor exhibited rod-like morphology, and their length increased with increased of the pH values. Under laser-diode excitation wavelength of 975 nm, the phosphor showed typical upconversion emission bands of the ion: strong green emission bands around 510-535/540-560 nm and weak red emission bands around 630-680 nm. The green and red emission intensity as a function of pH reached its maximum value at pH8. Finally, the emission intensity of","PeriodicalId":303178,"journal":{"name":"VNU Journal of Science: Mathematics - Physics","volume":"33 4-5 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2022-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"VNU Journal of Science: Mathematics - Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.25073/2588-1124/vnumap.4680","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
This paper reported the impact of pH on the structure, morphology, and the green upconversion (UC) emission of Er/Yb/Mo tri-doped hydroxyapatite (HA) synthesized through hydrothermal method. X-ray diffraction confirmed that the pH of the solution strongly influenced the phase composition of the phosphors, and HA single phase was obtained at a high pH value. Transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) images of the phosphor exhibited rod-like morphology, and their length increased with increased of the pH values. Under laser-diode excitation wavelength of 975 nm, the phosphor showed typical upconversion emission bands of the ion: strong green emission bands around 510-535/540-560 nm and weak red emission bands around 630-680 nm. The green and red emission intensity as a function of pH reached its maximum value at pH8. Finally, the emission intensity of