Effect of clay on the dielectric relaxation of ethylene propylene rubber using thermally stimulated discharge current measurements

A. Jeffery, D. Damon
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引用次数: 2

Abstract

Clay filler in EPR (ethylene propylene rubber) causes a peak in the TSDC (thermally stimulated discharge current) spectra at about 40 /spl deg/C. The peak displays dipole behavior and has an activation of 0.48eV. It seems to consist of one single relaxation peak and two smaller peaks which have not yet been analyzed. Reducing the clay concentration and particle size reduces the size of the peak. The polarization mechanism which causes this peak is not clear. It is possible that aggregation of the clay, adhesion of the clay to the polymer, or particle-particle interactions may affect this mechanism.<>
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用热激放电电流测量粘土对乙丙橡胶介电松弛的影响
在EPR(乙丙橡胶)中加入粘土填料,在TSDC(热激放电电流)光谱中出现约40 /spl℃的峰值。峰具有偶极子行为,激活度为0.48eV。它似乎由一个单一的松弛峰和两个尚未被分析的较小的峰组成。降低粘土浓度和颗粒尺寸减小峰的尺寸。引起此峰的极化机制尚不清楚。粘土的聚集、粘土与聚合物的粘附或颗粒间的相互作用可能会影响这一机制。
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