{"title":"Cathodic decomposition of propylene carbonate at graphite electrodes","authors":"T. Piao, C. Doh, S. Moon, Su-Moon Park","doi":"10.1109/BCAA.1997.574113","DOIUrl":null,"url":null,"abstract":"The decomposition reaction of propylene carbonate (PC) has been studied at graphite electrode in 1.0 M LiClO/sub 4/ employing a variety of transient electrochemical techniques. Results show that the PC decomposition reaction takes place through an EC' (electron transfer followed by catalytic reduction) reaction path. The pseudo first order rate constants of the chemical decomposition step has been determined. The formation of passive films on the electrode surface has been confirmed. The diffusion coefficients at the fresh and the film covered graphite electrodes have been determined to be 8.2/spl times/10/sup -9/ cm/sup 2//s and 7.1/spl times/10/sup -9/ cm/sup 2//s, respectively.","PeriodicalId":344507,"journal":{"name":"The Twelfth Annual Battery Conference on Applications and Advances","volume":"54 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1997-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Twelfth Annual Battery Conference on Applications and Advances","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/BCAA.1997.574113","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The decomposition reaction of propylene carbonate (PC) has been studied at graphite electrode in 1.0 M LiClO/sub 4/ employing a variety of transient electrochemical techniques. Results show that the PC decomposition reaction takes place through an EC' (electron transfer followed by catalytic reduction) reaction path. The pseudo first order rate constants of the chemical decomposition step has been determined. The formation of passive films on the electrode surface has been confirmed. The diffusion coefficients at the fresh and the film covered graphite electrodes have been determined to be 8.2/spl times/10/sup -9/ cm/sup 2//s and 7.1/spl times/10/sup -9/ cm/sup 2//s, respectively.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
