Weldability of 6% Superaustenitic Stainless Steel for Seawater Applications

T. Ogawa, T. Koseki
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引用次数: 7

Abstract

Corrosion resistant alloy welds for seawater applications are necessary to be over-alloyed with Cr, Mo and nitrogen to have an increased Pitting Index value. The desired weld chemistry also requires less microsegregation of Cr and Mo and precipitation free microstruciure not only for higher corrosion resistance but also for good mechanical properties and weld hot-cracking resistance. Based on such requisites for the welds, nitrogen-added Ni-based filler metal, 22Cr-60Ni-9Mo-0.1N, was developed for the welding of a 6%Mo superaustenitic stainless steel.The weldment by the newly developed filler metal showed excellent chloride corrosion resistance comparable to the base metal. The weld solidification and microstructure were fully austenitic without any other phases and brittle precipitates in the whole weld. Thereby, the weldment also offered good ductility, toughness and hot-cracking resistance superior to the weldment by the conventional Alloy 625 filler metal.
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海水用6%超奥氏体不锈钢的可焊性
海水应用的耐腐蚀合金焊缝必须与Cr、Mo和氮过度合金,以提高点蚀指数值。理想的焊缝化学性质还要求较少的Cr和Mo的微偏析和无析出的显微组织,不仅具有更高的耐腐蚀性,而且具有良好的机械性能和焊接热裂性。基于这些焊接要求,开发了用于焊接6%Mo超奥氏体不锈钢的添加氮的ni基填充金属22Cr-60Ni-9Mo-0.1N。新开发的钎料焊件具有与母材相当的优异的耐氯化物腐蚀性能。焊缝凝固和组织为完全奥氏体,无其他相和脆性析出物。因此,该焊件具有良好的延展性、韧性和抗热裂性,优于传统的Alloy 625填充金属焊件。
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