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Effect of TiC-Cr3C2 Particles Content on Abrasive Wear Resistance of Co-Base Overlay Weld Alloy. TiC-Cr3C2颗粒含量对共基堆焊合金磨料耐磨性的影响
Pub Date : 1993-10-01 DOI: 10.2207/QJJWS.11.156
M. Nishida, T. Araki, H. Fujita
This study was concerned with the production of carbide dispersion type composite materials by plasma transfer arc welding. The composite materials were produced by introducing different amounts of Cr-carbide and/or Ti-carbide powders in Co-base alloy (Stellite 6). To assess the resistance to wear of the composite materials, rubber wheel abrasion test was performed on surface of the composite materials.The composite materials were consisted of Co-alloy matrix and non-fused carbide. The average hardness of matrix was increased from HV450 to HV850 according to Cr-carbide content of the composite material.Weight loss of composite materials by wear were decreased from 850 mg to 50 mg according to volume fraction of non-fused carbide particles. Especially when mean free path between carbide particles was smaller than size silica sand (wear material), abrasive wear resistance of composite materials was rapidly improved.
研究了用等离子转移弧焊法制备碳化物分散型复合材料。在钴基合金(Stellite 6)中加入不同量的cr -碳化和/或ti -碳化粉末制备复合材料。为评估复合材料的耐磨性,在复合材料表面进行了橡胶轮磨损试验。复合材料由钴合金基体和未熔合硬质合金组成。随着复合材料中碳化物含量的增加,基体的平均硬度由HV450提高到HV850。根据未熔合碳化物颗粒的体积分数,复合材料的磨损失重从850 mg降低到50 mg。特别是当碳化物颗粒之间的平均自由程小于粒径的硅砂(磨损材料)时,复合材料的磨料耐磨性得到了迅速提高。
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引用次数: 7
Study on Glass-metal Bonding by Anodic Bonding. 玻璃金属阳极键合的研究。
Pub Date : 1993-10-01 DOI: 10.2207/QJJWS.11.208
M. Toyoda, Y. Fujiya, M. Nayama, Tadashi Yamada
Anodic bonding of glass and Si, which is performed by applying positive voltage of several hundred volt on Si, is well known as Mallory sealing process and has been in use. However, anodic bonding of glass and metal has not been comprehensively investigated and mechanism of the bonding has not been well understood.A fundamental study on anodic bonding of borosilicate glass and metal was carried out. Glass to Mo bonding and glass to Al bonding were successfully made, and glass to 304ss, glass to Ti, glass to Ni and glass to Au bondings were also made but they fractured at low stress level. Bonding test of glass and Mo using the design of experiment was carried out in order to specify dominant bonding parameters. Then, it has become clear that the bonding temperature and the applying voltage should be dominant in the range of bonding temperature of 400°C-600°C, applying voltage of 0 V-350 V, bonding time of 5 min-60 min, bonding pressure of 0.03 MPa-0.7 MPa in Ar atmosphere or in vacuum. Microscopic observations and chemical analysis were performed for glass to Mo bonded structure. The reaction zone between glass and Mo was not identified from the results of SEM and EPMA. Result of ESCA analysis revealed that Na, which was not found around the boundary, was detected in glass near the anode and Mo oxide was detected in glass near the boundary. Basing on the results, it has been considered that metal ions would diffuse into glass substituting for Na' and metal oxide be formed, then glass to metal bonding should be achieved.
玻璃与硅的阳极键合,是通过在硅上施加几百伏的正电压来实现的,被称为马洛里密封工艺,并已得到应用。然而,玻璃与金属的阳极键合还没有得到全面的研究,其键合机理也没有得到很好的了解。对硼硅玻璃与金属的阳极键合进行了基础研究。成功地实现了玻璃- Mo键合和玻璃- Al键合,也成功地实现了玻璃- 304ss键合、玻璃- Ti键合、玻璃- Ni键合和玻璃- Au键合,但它们在低应力水平下断裂。采用实验设计法进行了玻璃与钼的粘结试验,确定了主要的粘结参数。在氩气或真空条件下,焊温为400℃~ 600℃,焊电压为0 V ~ 350 V,焊时间为5 min ~ 60 min,焊压为0.03 MPa ~ 0.7 MPa。对玻璃-钼键合结构进行了显微观察和化学分析。SEM和EPMA均未发现玻璃与Mo之间的反应区。ESCA分析结果表明,在阳极附近的玻璃中检测到边界附近没有发现的Na,在边界附近的玻璃中检测到Mo氧化物。在此基础上,认为金属离子会扩散到玻璃中取代Na',形成金属氧化物,然后实现玻璃与金属的键合。
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引用次数: 5
Effects of Alloying Elements on the Toughness and Microstructure of HIGH CURRENT DENSITY GAS SHIELDED ARC PROCESS Weld Metals 合金元素对大电流密度气体保护电弧焊接金属韧性和显微组织的影响
Pub Date : 1993-10-01 DOI: 10.2207/QJJWS.11.29
S. Satonaka, K. Hari, Y. Matsumoto
Effects of thermal and physical properties of materials on the transient response of temperature to a step change in welding speed were investigated using TIG arc welding and FEM calculation of three-dimensional heat coduction. The materials used in this study were stainless steel, mild steel, aluminum alloy, brass and copper 9 mm in thickness.In TIG arc welding of low heat-conductive materials, large difference in maximum temperature appears in the period between former quasi-state and latter one. On the other hand, high heat-conductive materials indicate large difference in temperature gradient, but a little change in maximum temperature. In addition, the high heat-conductive materials require longer distance or time to be in latter quasi-state. The transient response from former to later quasi-state is characterized by the fraction of maximum temperature and temperature gradient to those at both quasi-states. These experimental results are confirmed by FEM calculations based on three-dimensional heat conduction. It is also clarified that although the maximum temperature mainly depend upon the thermal conductivity and thermal diffusivity, the transient response is dominated only on the thermal diffusivity. Therefore, the high thermal diffusive materials show slower response to a step change in welding speed.
采用TIG弧焊和三维热传导有限元计算方法,研究了材料的热性能和物理性能对温度随焊接速度阶跃变化的瞬态响应的影响。本研究使用的材料有不锈钢、低碳钢、铝合金、黄铜和9毫米厚的铜。在低导热材料的TIG电弧焊中,前准态与后准态期间的最高温度存在较大差异。另一方面,高导热材料的温度梯度差异较大,但最高温度变化不大。此外,高导热材料需要较长的距离或较长的时间才能处于后准态。从前态到后态的瞬态响应由最高温度和温度梯度与两个准态的比值表征。基于三维热传导的有限元计算证实了这些实验结果。虽然最高温度主要取决于热导率和热扩散率,但瞬态响应仅取决于热扩散率。因此,高热扩散材料对焊接速度阶跃变化的响应较慢。
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引用次数: 5
Impact Property at Cryogenic Temperature of Candidate Materials for Fusion Reactor and Their Electron Beam Welded Joint 核聚变反应堆候选材料及其电子束焊接接头的低温冲击性能
Pub Date : 1991-12-01 DOI: 10.2207/QJJWS.9.23
S. Kaga, I. Fukuhara, Katsuhiro Fujii, K. Ogawa, T. Baba, Yoshiaki Yamamoto
Impact properties at cryogenic temperature of candicate materials for fusion reactor and their electron beam welded joints are investigated by using instrumented Charpy impact testing apparatus. Material used are aluminum alloys (A7N01, A5083, A6061), JFMS (Japanese Ferritic Martensitic Steel) and two kinds of high manganese steels. Although JFMS is a steel for high temperature use, the impact test is conducted at low tenperature same as the cases of the other materials. Testing results are obtained as follows.1. Base metals and welded joints of aluminum alloys exhibit high absorbed energy at low temperature. Ductility of each base metal and welded joint gradually decreases with decreasing of testing temperature.2. Base metal and welded joint of JFMS exhibit an absorved energy transition temperature at near a room temperature.3. Base metal and welded joint of high manganese)steel A-T (18Mn) exhibit abrupt decreasing of absorbed energy at 77K, but base metal and welded joint of high manganese steel B-T (22Mn-0.2N) exhibit gradual increasing of maximum strength and decreasing of ductility with decreasing of testing temperature.
采用Charpy冲击试验装置,研究了核聚变反应堆候选材料及其电子束焊接接头的低温冲击性能。所用材料有铝合金(A7N01、A5083、A6061)、JFMS(日本铁素体马氏体钢)和两种高锰钢。虽然JFMS是一种高温用钢,但与其他材料的情况一样,冲击试验是在低温下进行的。测试结果如下:1。贱金属和铝合金的焊接接头在低温下具有较高的吸收能。随着试验温度的降低,各母材和焊接接头的塑性逐渐降低。JFMS的母材和焊接接头在接近室温时表现出吸收的能量转变温度。高锰钢A-T (18Mn)母材和焊接接头在77K时吸收能急剧下降,而高锰钢B-T (22Mn-0.2N)母材和焊接接头随着试验温度的降低,最大强度逐渐升高,塑性逐渐降低。
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引用次数: 1
Influence of Delta-ferrite on Sensitization of the Austenitic Stainless Steel Weld Metal δ -铁素体对奥氏体不锈钢焊缝金属敏化的影响
Pub Date : 1991-03-10 DOI: 10.2207/QJJWS.9.415
Y. Nakao, K. Nishimoto, M. Ishizaki
Sensitization behavior of the delta-ferrite containing stainless steel weld metal was investigated using Type 304 and Type 308 alloys with the carbon content ranging from 0.04% to 0.09%, respective-ly. The weld metals heat treated at 923 K for times varying between 1 sec and 100 hr were tested for intergranular corrosion susceptibility in the acidified copper sulfate solution. The delta ferrite contain-ing weld metal with lower carbon content indicated rapidly healing of sensitization after the short heat treatment, whereas ones with higher carbon content than a critical value behaved as a fully austenitic steel regardless the existence of ferrite without showing the sign of rapid healing. SEM observation revealed that M23C6 precipitated preferentially at the ferrite-austenite boundary and also at the austenite-austenite boundaries although its amount at the latter boundaries was much less than the other in the both weld metals which indicated rapid healing of sensitization and behaved as a fully austenitic steel. A mathematical model is developed for the sensitization of the ferrite containing austenitic stainless steel weld metal. The degree of sensitization calculated using this model has shown a good agreement with the experimental corrosion test results. The calculation also demonstrated that for a given carbon content there exist the critical values for not only the total amount but the thickness of ferrite, above which the weld metal develop the rapid healing of sensitization.
采用含碳量分别为0.04% ~ 0.09%的304型和308型合金,研究了含δ -铁素体不锈钢焊缝金属的敏化行为。在923 K下热处理1秒至100小时的焊缝金属在酸化硫酸铜溶液中进行了晶间腐蚀敏感性测试。含δ铁素体的低碳焊缝金属在短时间热处理后敏化迅速愈合,而含碳量高于临界值的焊缝金属即使有铁素体存在,也表现为完全奥氏体钢而不表现出快速愈合的迹象。SEM观察发现,M23C6在铁素体-奥氏体边界和奥氏体-奥氏体边界的析出优先,但在奥氏体-奥氏体边界的析出量要少得多,表明敏化愈合迅速,表现为完全奥氏体钢。建立了含铁素体奥氏体不锈钢焊缝金属敏化的数学模型。利用该模型计算的敏化度与试验腐蚀试验结果吻合较好。计算还表明,在一定碳含量下,不仅铁素体的总量,而且铁素体的厚度都存在一定的临界值,超过这个临界值,焊缝金属就会发生敏化的快速愈合。
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引用次数: 12
Newly developed micro-parallel seam joining equipment and its applications. Micro-parallel seam joining and development of joining equipment(4th Report). 新型微平行缝连接设备及其应用。微平行缝连接及连接设备的研制(第四次报告)。
Pub Date : 1989-11-05 DOI: 10.2207/QJJWS.7.425
Susumu Aono, K. Ohmori, Masaki Furuya, T. Takakura
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引用次数: 2
The Nitrogen Absorption of Iron Weld Metal by Gas Tungsten Arc Welding 钨气弧焊对铁焊缝金属氮的吸收
Pub Date : 1986-04-01 DOI: 10.2207/QJJWS.1.392
T. Kuwana, H. Kokawa
ア ーク溶接過程におけるガス ・メタル反応を明 らかに す ることは,溶 接工学上重要な課題で ある.著 者 らは こ れまで消耗電極式 アーク溶接(GMAW)に お ける軟 鋼 および鉄合金溶接金属の 窒 素 吸 収 に関 して 一 連 の 研 究 を行い,溶 接金属 中の窒素の冶金物理化学的な挙 動を明 らか にして きた.し か し消耗電極法を用 いた場合 には電極線 と母材 とが同時 に溶融するため,諸 現象を解 析す るに際 して幾分複雑な面があ ることは否め ない.例 えば消耗電極法では,溶 滴の形成および移行 の過程です でに窒素吸収反応 が生 じたり,電 極線 と母材の化学組成 の差が窒素吸収に影響を与 えるこ とが考 え られ るか らで あ る. 本研究は,窒 素吸収に関与す る因子 をできるだ け少な くし,よ り単純な状況下で溶接金 属の窒素吸収挙動 に関 す る基礎的.資料 を得ることを 目的 と して いる.す なわ ち,タ ングステ ン電極 による非消耗電極法を用 い窒素お よび窒素を含む各 種溶接雰囲気中で純鉄 に近い化学組成 の鉄を アーク溶接 し,溶 接金属の窒素吸収 におよぼす溶 接条件 および雰囲気 の影響 などについて調べ,化 学冶金 学的な考察を行 った.
弄清电弧焊接过程中的气体和金属反应是熔接工学上的重要课题。作者们对消耗电极式电弧焊接(GMAW)中软钢和铁合金焊接金属的氮吸收进行了一系列研究,熔接金属中氮的冶金物理化学的实例但不可否认的是,使用消耗极电极法时,由于电极导线和母材同时熔融,在分析各种现象时存在一些复杂的方面。例如,在消耗极电极法中,考虑到在溶滴的形成及转移过程中会产生氮气吸收反应,电极线和母材化学组成的差异会影响氮气吸收。本研究是在尽可能少的影响氮气吸收的情况下,在比较简单的情况下焊接金属的氮气吸收行为的基础研究。以获取资料为目的,采用采用砂和钨电极的非消耗极电极法,在含氮和含氮的各种焊接氛围中,将化学组成接近纯铁的铁弧焊,然后熔化。调查了对接触金属的氮吸收的熔接条件和气氛的影响等,进行了化学和冶金学的考察。
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引用次数: 7
The Effect of the Nitrogen Absorption on the TEM Structure of SUS304L Austenitic Stainless Steel Weld Metal 氮吸收对SUS304L奥氏体不锈钢焊缝TEM组织的影响
Pub Date : 1986-04-01 DOI: 10.2207/qjjws.4.520
T. Kuwana, H. Kokawa, H. Tsujii
The effect of the nitrogen absorption on the transmission electron microscopic structure of SUS304L austenitic stainless steel weld metal was investigated by varying the nitrogen partial pressure of the Ar-N2 gas mixture welding atmosphere in an atmosphere-controlling chamber. An electron diffraction study suggested that the primary solidification mode of the weld metal alters from ferritic mode to austenitic one with the nitrogen partial pressure and the nitrogen content of weld metal. The austenite frequently adopts a near Kurdjumov-Sachs orientation relationship with the adjacent primary ferrite, while the eutectic ferrite does not adopt the K-S one with the adjacent austenite. The amount of the eutectic ferrite phase increases with the nitrogen partial pressure and the nitrogen content. In the weld metal with no ferrite, precipitation on dislocations and grain boundaries was observed.
通过在气氛控制室中改变Ar-N2混合气体焊接气氛的氮气分压,研究了氮气吸收对SUS304L奥氏体不锈钢焊缝金属透射电镜组织的影响。电子衍射分析表明,随着氮分压和焊缝金属含氮量的增加,焊缝金属的初次凝固模式由铁素体转变为奥氏体。奥氏体与邻近的原生铁素体往往采用接近kurdjumovo - sachs取向关系,而共晶铁素体与邻近的奥氏体不采用K-S取向关系。共晶铁素体相的数量随着氮分压和氮含量的增加而增加。在不含铁素体的焊缝金属中,观察到位错和晶界的析出。
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引用次数: 9
The Reheated Zone Toughness of Multipass Weld Metal (Report 1) : Comparison of Reheated Zone Toughness between Si-Mn System and High Strength Low Alloy System Weld Metals 多道焊缝金属的再热区韧性(报告1):Si-Mn体系与高强度低合金体系焊缝金属再热区韧性的比较
Pub Date : 1983-04-01 DOI: 10.2207/QJJWS1943.51.359
Y. Kikuta, T. Araki, M. Yoneda, H. Yoshida, T. Suga
The weld construction using heavy section steel and/or high strength low alloy steel is made by multipass welding. In that case, weld metal is reheated to various temperatures by welding heat of the subsequent pass. This result will lead to both microstructural change and through thickness toughness variation in weld metal.In this work, an investigation was carried out about the reheated zone toughness in weld metal.It is found by this work that, for simple Si-Mn system weld metal, the reheated zone toughness is improved as compared with as-welded touhgness, and increases with the ratio of reheated structure to aswelded structure. This improvement is caused by both the disappearance of columnar structure and the refinement of microstructure.While, for high strength low alloy system weld metal, the reheating shows the complex effect. The reheated zone toughness in this system deteriorates at peak temperature range between 750°C and 950°C, although the remarkable optical microstructural change is not observed.The reheating effect to the toughness of high strength low alloy system weld metal shows the inverse phenomenon as compared with that to the toughness of simple Si-Mn system weld metal.
采用大型钢和/或高强度低合金钢的焊缝结构采用多道焊接。在这种情况下,焊接金属通过随后的焊接热被重新加热到不同的温度。这一结果将导致焊缝金属的显微组织变化和厚度韧性变化。本文对焊接金属的再热区韧性进行了研究。研究发现,对于简单Si-Mn系焊缝金属,再加热区韧性较焊态韧性有所提高,且随着再加热组织与焊态组织的比例增加而增加。这种改善是由于柱状组织的消失和组织的细化所致。而对于高强度低合金系焊缝金属,再加热效果复杂。该体系的再热区韧性在750℃~ 950℃的峰值温度范围内恶化,但没有观察到明显的光学显微组织变化。再加热对高强度低合金体系焊缝金属韧性的影响与对简单Si-Mn体系焊缝金属韧性的影响相反。
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引用次数: 1
Kinetics of the Formation of Austenite at Constant Temperature : Study on the Phase Transformation in Welded Joints of Duplex Satinless Steels (Report 1) 奥氏体在恒温下形成的动力学——双相无锦缎钢焊接接头相变的研究(报告1)
Pub Date : 1982-10-01 DOI: 10.2207/QJJWS1943.50.514
Y. Nakao, K. Nishimoto, S. Inoue
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引用次数: 11
期刊
Transactions of the Japan Welding Society
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