INFLUENCE OF MULTI-WALLED CARBON NANOTUBES CONTENT ON THE MECHANICAL PROPERTIES OF COLD AND HOT CURED ACRYLIC RESIN FOR DENTURE BASE.

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Abstract

The main objective of this work is to investigate the effect of multi-walled carbon nanotubes (MWCNTs) on the mechanical properties of polymethyl methacrylate (PMMA) reinforced by MWCNTs of 0.1, 0.2, 0.3, 0.4 and 0.5 wt. % contents. The mechanical properties investigated in the present study are compressive strength, apparent modulus of elasticity, modulus of resilience, modulus of toughness and ductility at yield. PMMA is prepared at both hot and cold acrylic resins to be used as denture base materials. Compression test was considered as a useful tool to describe the mechanical properties of the PMMA/ MWCNTs tested composites. The tests have been carried out on a digital controlled universal testing machine. Based on the experiments, it is shown that the mechanical properties of the cold PMMA were higher than that measured for the hot at 0 wt. %, MWCNTs, while at 0.1 wt. %, the mechanical properties of the hot MWCNTs/PMMA composites were higher than the cold ones. On the other hand, it was found that after 0.1 wt. %, with increasing MWCNTs content the mechanical properties decreased gradually for both cold and hot composites. The improvement in the strength at 0.1 wt. % may be due to the interfacial shear strength between nanofiller and matrix that was relatively high due to formation of cross links or supra molecular bonding which cover or shield the nanofiller that in turn prevent propagation of crack. From this study, it can be concluded that hot cured composites are better than cold cured composites as denture base materials.
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多壁碳纳米管含量对义齿基托用冷、热固化丙烯酸树脂力学性能的影响
本研究的主要目的是研究多壁碳纳米管(MWCNTs)对重量分别为0.1、0.2、0.3、0.4和0.5 wt %的MWCNTs增强聚甲基丙烯酸甲酯(PMMA)力学性能的影响。本研究研究的力学性能包括抗压强度、表观弹性模量、回弹模量、韧性模量和屈服延性。PMMA是在热和冷两种丙烯酸树脂条件下制备的义齿基托材料。压缩试验被认为是描述PMMA/ MWCNTs测试复合材料力学性能的有用工具。试验在数控通用试验机上进行。实验结果表明,当MWCNTs重量为0 wt. %时,冷态PMMA的力学性能高于热态,而当MWCNTs重量为0.1 wt. %时,热态MWCNTs/PMMA复合材料的力学性能高于冷态。另一方面,在0.1 wt. %之后,随着MWCNTs含量的增加,冷、热复合材料的力学性能逐渐下降。在0.1 wt. %时,强度的提高可能是由于纳米填料和基体之间的界面剪切强度相对较高,这是由于交联或超分子键的形成,覆盖或屏蔽了纳米填料,从而防止了裂纹的扩展。从本研究中可以得出结论,热固化复合材料作为义齿基托材料优于冷固化复合材料。
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