Gd and Nd Doped Perovskite – Potential Material for Sustainable Energy

Md. Soaib Khan, R. Ranjan, Sweta Sharma, A. Srivastava
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Abstract

With the steady advancement of human civilization, energy lack and ecological contamination have become an ever-increasing number of critical difficulties in our reality, and they are issues that should be settled desperately. Perovskite, a potential material for sustainable ideal energy source, boundless, and clean energy. Perovskite with general formula ABX3 plays an important role in electrode and electrolyte for solar cells which is most ideal alternatives to silicon solar cells, supercapacitor, Bio fuel and solid oxide fuel etc. because of their stability, ferroelectric, supreme, catalytic, dielectric and high charge carrier mobility. In this paper the perovskite doped with rare earth Gd and Nd was synthesise by a solid reaction technique at high temperature. XRD confirms the tetragonal structure of single step. Dielectric behaviour of PVSK ceramics was studied using CIS technique within range of 9000C to 12500C and frequency range of 1 kHz and 1 MHz the existence of the ac conductivity variance indicates the electrical conductivity form of Arrhenius. The dielectric constant of the materials is very high which is needed for the energy storage device. The material's tangent loss is very low until the transition temperature is very high. The tolerance factor of PVSK material was found to be nearly 1.
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Gd和Nd掺杂钙钛矿-可持续能源的潜在材料
随着人类文明的不断进步,能源短缺和生态污染已成为我们日益突出的现实难题,是亟待解决的问题。钙钛矿是一种潜在的可持续理想能源材料,是无限量的清洁能源。钙钛矿具有稳定性、铁电性、超强性、催化性、介电性和高载流子迁移率等优点,在太阳能电池的电极和电解质中起着重要的作用,是硅太阳能电池、超级电容器、生物燃料和固体氧化物燃料等的理想替代品。本文采用固相反应技术在高温下合成了稀土掺杂Gd和Nd的钙钛矿。XRD证实了单台阶的四方结构。采用CIS技术研究了PVSK陶瓷在9000C ~ 12500C、1khz和1mhz频率范围内的介电行为,电导率变化的存在表明了Arrhenius的电导率形式。材料的介电常数非常高,这是储能装置所需要的。在转变温度很高之前,材料的切损都很低。PVSK材料的容差系数接近1。
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