Green Zeolite Synthesis Assisted with Plants Extract

Dee Tee, Faiz Hafeez Azhar, Z. Harun, R. Hussin, Syamsutajri Syamsol Bahri, N. Hairom, A. Ainuddin, H. Basri, Z. Kamdi
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Abstract

The study explores the hydrothermal synthesis of zeolite using kaolin clay from Perak in the presence of two different reduction mediums, namely turmeric extract and ginger extract, and a 2M NaOH solution, measuring their efficiency and potential for green synthesis. Before the zeolite synthesis and transformation, the kaolin clay was heated at a temperature of 650 oC for 4 hours in the furnace to produce the metakaolin phase. The synthesized zeolite involves the reaction of NaOH with potential reduction plant extracts to assist the transformation of zeolite. The characterization of the synthesized particles after being ground into a fine powder and subsequently undergoing testing and characterization via X-ray diffraction (XRD) revealed the existence of zeolite phases in both plants with slightly different zeolite compositions. Synthesis mixtures with turmeric plants show better composition of the zeolite phase as compared to ginger mixtures. Scanning Electron Microscope (SEM) and Energy Dispersive X-Ray Analysis (EDX) also revealed that the synthesized product using turmeric plant extract was able to produce zeolite LTA with a good grade. The current experimental work shows the possibility of obtaining a well crystalline zeolite from Malaysian kaolin, assisted with plant extract reduction medium.
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植物提取物辅助合成绿色沸石
本研究探索了用霹雳州高岭土在两种不同还原介质(姜黄提取物和生姜提取物)和2M NaOH溶液存在下水热合成沸石的方法,并测量了它们的效率和绿色合成的潜力。沸石合成转化前,将高岭土在炉内650℃加热4小时,生成偏高岭土相。合成的沸石是NaOH与电位还原植物提取物的反应,以辅助沸石的转化。将合成的颗粒磨成细粉后进行表征,随后通过x射线衍射(XRD)进行测试和表征,发现两种植物中存在沸石相,但沸石成分略有不同。与姜黄植物合成混合物相比,姜黄植物合成混合物具有更好的沸石相组成。扫描电镜(SEM)和能量色散x射线分析(EDX)也表明,用姜黄植物提取物合成的产物能够生产出质量优良的沸石LTA。目前的实验工作表明,在植物提取物还原介质的辅助下,可以从马来西亚高岭土中获得结晶良好的沸石。
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