Experimental measurement of E to H mode transition in O2, N2 and O2-N2 gases in cylindrical ICP source for photoresist dry-strip applications

S. Nawaz, H. Rhee, D. H. Kim, S. Yoon
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Abstract

Summary form only given. Inductively coupled plasmas (ICP) have attracted widespread interest in semiconductor fabrication processes due to attractive properties including high plasma density and low contamination that are available under low-pressure. We report the characteristics of E-H mode transition changes at various gas mixtures in the pressure controlled chamber. Our discharge chamber, which was designed for photoresist dry-strip process, had 200mm diameter and consisted of three-turn external cylindrical antenna coil which sustained 13.56 MHz RF power through pi-type matching network. Generation of O radical is of great interest for dry-strip process in semiconductor industry in order to remove photoresist (PR) deposited on wafer. Mixture of N2 in the O2 plasma increases portion of O radical due to collision of two molecules 1. It is of interest to evaluate the EH mode transition power at various gas mixture for better understand the process tool. The voltage and current on the coil are measured with a high voltage probe and a current sensor. The preliminary results show that the transition from E to H mode occurs at relatively low power for pure oxygen than pure nitrogen and gas mixture. The energy loss via collision and electron-neutral collision frequency for N2 molecules are greater than O2 which requires higher transition ICP power. Moreover PR strip rate was compared at different gas mixture in order to compare O radical generation. Total PR strip amount was compared for changing the ratio of two gas mixture. The experimental results show the total PR strip amount is increased for mixing N2 among O2 plasma. These results will be considered to operate efficient ICP source and to optimize the process condition for PR dry-strip process.
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用于光刻胶干条应用的圆柱形ICP源中O2、N2和O2-N2气体中E到H模式跃迁的实验测量
只提供摘要形式。电感耦合等离子体(ICP)在半导体制造工艺中引起了广泛的兴趣,因为它具有高等离子体密度和低污染的特性,可以在低压下使用。本文报道了在压控室中不同气体混合物下E-H模式转变的特征。放电室为光刻胶干条工艺设计,直径200mm,由三匝外圆柱形天线线圈组成,通过pi型匹配网络持续13.56 MHz射频功率。为了去除沉积在硅片上的光刻胶(PR), O自由基的产生是半导体工业干带工艺的重要研究方向。O2等离子体中N2的混合由于两个分子的碰撞而增加了O自由基的部分。为了更好地理解工艺工具,对不同气体混合物下的EH模式转换功率进行评估是有意义的。用高压探头和电流传感器测量线圈上的电压和电流。初步结果表明,纯氧比纯氮和混合气体在较低的功率下从E模式转变为H模式。N2分子的碰撞能量损失和电子中性碰撞频率均大于O2,对跃迁ICP功率要求较高。此外,还比较了不同气体混合条件下的PR条带率,以比较O自由基的生成情况。通过改变两种气体混合物的比例,比较了总PR条量。实验结果表明,在O2等离子体中混合N2可提高PR条总量。这些结果将被认为是有效运行ICP源和优化PR干带工艺条件的依据。
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