Photoluminescence enhancement and quenching of ZnS:Mn2+ in the presence of Au and Ag nanoparticles synthesized by pulse laser ablation in solution.

Tran Trong Duc, Bui Hong Van, Nguyen The Binh
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Abstract

Abstract: Gold (Au) and silver (Ag) nanoparticles were synthesized by laser ablation in water. The average sizes of Au and Ag nanoparticles are 18,4 nm and 21,8 nm respectively. ZnS:Mn2+ nanoparticles with average size of 3-5 nm were prepared by a co-precipitation method. The photoluminescence of ZnS:Mn2+solution in mixture with Au (Ag) nanoparticle colloids was investigated. The quenching effect on Mn2+ emission at 601 nm band were observed in the presence of the Au and Ag nanoparticles while the D-A emission at 445 nm band was enhanced and blue shifted by Au nanoparticles . The results and discussion are presented in this report.  
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溶液中脉冲激光烧蚀合成的Au和Ag纳米粒子存在下ZnS:Mn2+的光致发光增强和猝灭。
摘要:采用激光烧蚀法在水中合成了金(Au)和银(Ag)纳米颗粒。Au和Ag纳米粒子的平均尺寸分别为18.4 nm和21.8 nm。采用共沉淀法制备了平均粒径为3 ~ 5 nm的ZnS:Mn2+纳米颗粒。研究了ZnS:Mn2+溶液与Au (Ag)纳米颗粒胶体混合的光致发光特性。Au和Ag纳米粒子对Mn2+在601 nm波段的发射有猝灭作用,而Au纳米粒子对445 nm波段的D-A发射有增强和蓝移作用。结果和讨论在本报告中提出。
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