Effect of Sn on formation and transformation of VO2 phase

Hao. Dong, Dechen Shang, Yanxue Lu, Yu-tong Li, Fanxin Wu, Jun-wei Zhang
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Abstract

The role of Stannum was investigated in formation and transformation of Vanadium-Dioxide phase in a deep perspective through characterization methods including Raman spectra, XRD, OM, SEM, UV-vis and Electrochemical Workstation. The result showed supersaturated Stannum atoms could exist in SnxV2-xO5 as amorphous solid solution from non-equilibrium sputtering method, by which the unitary phase Sn-doped VO2 could be obtained under either thermal de-oxidation or thermal de-composition mechanism. Furthermore, the cooperation stannum atoms with oxygen vacancies could regulate the formation of vanadium dioxide M1 or M2 phase, in turn engineer the phase transformation (M-R) temperature of VO2.
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Sn对VO2相形成和转变的影响
通过拉曼光谱、XRD、OM、SEM、UV-vis和电化学工作站等表征方法,深入研究了锡在二氧化钒相形成和转变中的作用。结果表明:非平衡溅射法在snx_2 - xo5中可以存在过饱和的锡原子作为非晶固溶体,通过热脱氧或热分解机制可以得到单一相的sn掺杂VO2。此外,锡原子与氧空位的协同作用可以调节二氧化钒M1或M2相的形成,进而控制VO2的相变温度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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