Sol-Gel Synthesis of Nanosized Powders and Obtaining Ceramic Composites Based on Zircon and Zirconium Oxide

IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS Glass Physics and Chemistry Pub Date : 2023-11-16 DOI:10.1134/S1087659623600540
V. L. Ugolkov, N. A. Koval’chuk, A. V. Osipov, L. P. Mezentseva
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Abstract

Nanosized precursor powders of (1 – x)ZrSiO4xZrO(OH)2 are synthesized by the sol-gel method with the separate precipitation of components to obtain (1 – x)ZrSiO4xZrO2 ceramic composites. The thermal behavior of precursor powders is studied by differential scanning calorimetry and thermogravimetry (DSC/TG). Ceramic composites with a high level of microhardness are obtained by sintering powders, preliminarily calcined at 850°C, in air in the temperature range 1000‒1300°C. In the future, such ceramic composites can be used as matrices for solidification and isolating high-level waste (HLW).

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溶胶-凝胶法制备纳米粉体及锆/氧化锆陶瓷复合材料
采用溶胶-凝胶法合成(1 - x) ZrSiO4-xZrO (OH)2纳米前驱体粉末,组分分离沉淀,得到(1 - x) ZrSiO4-xZrO (OH)2陶瓷复合材料。采用差示扫描量热法和热重法(DSC/TG)研究了前驱体粉末的热行为。高显微硬度的陶瓷复合材料是通过烧结粉末,在850°C的温度下,在1000-1300°C的温度范围内进行初步煅烧得到的。在未来,这种陶瓷复合材料可以用作固化和隔离高放废物(HLW)的基体。
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来源期刊
Glass Physics and Chemistry
Glass Physics and Chemistry 工程技术-材料科学:硅酸盐
CiteScore
1.20
自引率
14.30%
发文量
46
审稿时长
6-12 weeks
期刊介绍: Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
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