Thermodynamic Evaluation of the Surface Tension and Viscosity of Liquid Quaternary Alloys: The Ti-Al-Cr-Nb System

IF 1.3 4区 工程技术 Q2 ENGINEERING, AEROSPACE Microgravity Science and Technology Pub Date : 2023-10-26 DOI:10.1007/s12217-023-10080-x
Rada Novakovic, Donatella Giuranno, Markus Mohr, Hans-Jöerg Fecht
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Abstract

Surface tension and viscosity of complex Ti-based industrial alloys are important for simulation of liquid assisted industrial processes such as casting, joining, crystal growth and infiltration. Modelling of the interface and mass transport during liquid-solid phase transition requires reliable surface tension and viscosity data. Therefore, to obtain accurate predictions of microstructural evolution during solidification related processes, only reliable input data are necessary. In the case of liquid Ti-Al alloys, the experimental difficulties related to high temperature measurements and reactivity of these alloys with supporting materials or containers as well as inevitable presence of oxygen may lead to data gaps including a complete lack of property data. An alternative for container-based methods are containerless processing techniques that offer a significant accuracy improvement and / or make possible to measure temperature and composition dependent thermophysical properties of metallic melts, as in the case of the Ti-Al-Cr-Nb system. Advanced mathematical models and computer simulations, developed in several theoretical frameworks, can be used to compensate the missing data; on the other side, for the validation of theoretical models, the experimental data are used. In the present work, an evaluation of the surface tension and viscosity of liquid Ti-Al-Cr-Nb alloys by means of the predictive models and a comparison to the available experimental data were done. The proposed methodology is a tool to assess the reliability of thermophysical properties data of multicomponent alloy systems.

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液态季系合金表面张力和粘度的热力学评价:Ti-Al-Cr-Nb体系
复杂钛基工业合金的表面张力和粘度对于模拟液体辅助工业过程(如铸造、连接、晶体生长和渗透)具有重要意义。在液固相变过程中,界面和质量传递的建模需要可靠的表面张力和粘度数据。因此,要获得凝固相关过程中组织演变的准确预测,只需要可靠的输入数据。在液态Ti-Al合金的情况下,高温测量和这些合金与支撑材料或容器的反应性以及不可避免的氧气存在相关的实验困难可能导致数据空白,包括完全缺乏性能数据。基于容器的方法的另一种替代方法是无容器处理技术,它提供了显着的精度改进和/或使测量金属熔体的温度和成分依赖的热物理性质成为可能,例如Ti-Al-Cr-Nb系统。在几个理论框架中开发的先进数学模型和计算机模拟可以用来补偿缺失的数据;另一方面,为了验证理论模型,使用了实验数据。本文利用预测模型对液态Ti-Al-Cr-Nb合金的表面张力和粘度进行了评估,并与已有的实验数据进行了比较。提出的方法是一种评估多组分合金系统热物性数据可靠性的工具。
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来源期刊
Microgravity Science and Technology
Microgravity Science and Technology 工程技术-工程:宇航
CiteScore
3.50
自引率
44.40%
发文量
96
期刊介绍: Microgravity Science and Technology – An International Journal for Microgravity and Space Exploration Related Research is a is a peer-reviewed scientific journal concerned with all topics, experimental as well as theoretical, related to research carried out under conditions of altered gravity. Microgravity Science and Technology publishes papers dealing with studies performed on and prepared for platforms that provide real microgravity conditions (such as drop towers, parabolic flights, sounding rockets, reentry capsules and orbiting platforms), and on ground-based facilities aiming to simulate microgravity conditions on earth (such as levitrons, clinostats, random positioning machines, bed rest facilities, and micro-scale or neutral buoyancy facilities) or providing artificial gravity conditions (such as centrifuges). Data from preparatory tests, hardware and instrumentation developments, lessons learnt as well as theoretical gravity-related considerations are welcome. Included science disciplines with gravity-related topics are: − materials science − fluid mechanics − process engineering − physics − chemistry − heat and mass transfer − gravitational biology − radiation biology − exobiology and astrobiology − human physiology
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