Method for Obtaining Isothermal Diagrams of the Liquid - Vapor Equilibrium for the System as Dimethyl Zinc - Dimethyl Telluride

Serhiy Gerasymchuk, Ihor Poliuzhyn, Valentyn Serheyev, Tetiana Hnativ
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Abstract

According to the obtained experimental temperature dependences of the saturated vapor pressure on dimethylzinc – dimethyltelluride solutions with dimethylzinc content of 50.0 and 70.32 mol. %, isothermal sections (280, 290, 300, 310, and 320 K) were made. For the dimethylzinc – dimethyltelluride system based on a limited set of experimental data for the “liquid-vapor” equilibrium, the vapor composition was calculated according to the Duhem – Margules equation, as well as the partial pressures and the distribution coefficient.
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二甲基锌-碲化二甲基体系液-气平衡等温图的求取方法
根据二甲基锌-二甲基碲化物溶液饱和蒸汽压在二甲基锌含量为50.0和70.32 mol. %时的温度依赖性,分别在280、290、300、310和320 K处进行等温截面。对于二甲基锌-二甲基碲化物体系,基于有限的“液-气”平衡实验数据,根据Duhem - Margules方程、分压和分布系数计算了其蒸汽组成。
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