Anna A. Rybkina, Alevtina A. Gogina, Artem V. Tarasov, Ye Xin, Vladimir Yu. Voroshnin, Dmitrii A. Pudikov, Ilya I. Klimovskikh, Anatoly E. Petukhov, Kirill A. Bokai, Chengxun Yuan, Zhongxiang Zhou, Alexander M. Shikin, Artem G. Rybkin
{"title":"Origin of Giant Rashba Effect in Graphene on Pt/SiC","authors":"Anna A. Rybkina, Alevtina A. Gogina, Artem V. Tarasov, Ye Xin, Vladimir Yu. Voroshnin, Dmitrii A. Pudikov, Ilya I. Klimovskikh, Anatoly E. Petukhov, Kirill A. Bokai, Chengxun Yuan, Zhongxiang Zhou, Alexander M. Shikin, Artem G. Rybkin","doi":"10.3390/sym15112052","DOIUrl":null,"url":null,"abstract":"Intercalation of noble metals can produce giant Rashba-type spin–orbit splittings in graphene. The spin–orbit splitting of more than 100 meV has yet to be achieved in graphene on metal or semiconductor substrates. Here, we report the p-type graphene obtained by Pt intercalation of zero-layer graphene on SiC substrate. The spin splitting of ∼200 meV was observed at a wide range of binding energies. Comparing the results of theoretical studies of different models with the experimental ones measured by spin-ARPES, XPS and STM methods, we concluded that inducing giant spin–orbit splitting requires not only a relatively close distance between graphene and Pt layer but also the presence of graphene corrugation caused by a non-flat Pt layer. This makes it possible to find a compromise between strong hybridization and increased spin–orbit interaction. In our case, the Pt submonolayer possesses nanometer-scale lateral ordering under graphene.","PeriodicalId":48874,"journal":{"name":"Symmetry-Basel","volume":null,"pages":null},"PeriodicalIF":2.2000,"publicationDate":"2023-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Symmetry-Basel","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/sym15112052","RegionNum":3,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Intercalation of noble metals can produce giant Rashba-type spin–orbit splittings in graphene. The spin–orbit splitting of more than 100 meV has yet to be achieved in graphene on metal or semiconductor substrates. Here, we report the p-type graphene obtained by Pt intercalation of zero-layer graphene on SiC substrate. The spin splitting of ∼200 meV was observed at a wide range of binding energies. Comparing the results of theoretical studies of different models with the experimental ones measured by spin-ARPES, XPS and STM methods, we concluded that inducing giant spin–orbit splitting requires not only a relatively close distance between graphene and Pt layer but also the presence of graphene corrugation caused by a non-flat Pt layer. This makes it possible to find a compromise between strong hybridization and increased spin–orbit interaction. In our case, the Pt submonolayer possesses nanometer-scale lateral ordering under graphene.
期刊介绍:
Symmetry (ISSN 2073-8994), an international and interdisciplinary scientific journal, publishes reviews, regular research papers and short notes. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. There is no restriction on the length of the papers. Full experimental and/or methodical details must be provided, so that results can be reproduced.