Total Energy and Total Power for the SOEC: Critical Role of Area Specific Resistance in Hydrogen Production Rate

Mark Williams
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Abstract

This paper develops the governing Total Energy (TE) (kilowatt-hours per kilogram hydrogen) and Total Power (TP) equations for Solid Oxide ElectrolyzerCells (SOECs) and Solid Oxide Fuel Cells (SOFCs). The TE equation includes heat input, exergetic flows, enthalpy of vaporization, pressurization, heat loss, area specific resistance (ASR), etc. The TE equation developed, as it would happen, correlates well with the Idaho National Laboratory (INL) proven SOEC performance of 45 kilowatt-hours per kilogram hydrogen at 20 bars and 725 K. TE is the key performance equation necessary for designing, predicting, and planning for SOEC and SOFC performance and cost. The ASR has a critical role in SOEC TE and TP. The ASR and the targets for ASR necessary to meet important DOE performance targets are discussed.
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SOEC的总能量和总功率:面积比电阻在产氢率中的关键作用
本文建立了固体氧化物电解质电池(SOECs)和固体氧化物燃料电池(sofc)的总能量(TE)(每千克氢千瓦时)和总功率(TP)方程。TE方程包括热输入、火用流量、蒸发焓、加压、热损失、面积比阻(ASR)等。所开发的TE方程与爱达荷国家实验室(INL)证明的在20巴和725 K条件下每千克氢45千瓦时的SOEC性能非常吻合。TE是设计、预测和规划SOEC和SOFC性能和成本所需的关键性能方程。ASR在SOEC TE和TP中起关键作用。讨论了满足DOE重要性能指标所需的ASR和ASR指标。
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