(Digital Only Presentation) Effects of Ink Solvent on the Screen-Printing Fabrication and Morphology of LSM-YSZ Thin Films Deposited on YSZ Substrate for Solid Oxide Electrochemical Cells

Jessa Hablado, Rinlee Cervera
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Abstract

Screen-printing is a cheap and easy thin film deposition technique utilized in energy devices fabrication, specifically, in solid oxide electrochemical cells (SOCs). In this study, LSM-YSZ, a promising component material for SOCs application was deposited on YSZ electrolyte via screen-printing. Specifically, the study aimed to investigate the effect of the solvent used in screen-printing and the effect of varying ink formulation on the quality of the deposited film. LSM-YSZ precursor powders synthesized via glycine-nitrate combustion process (GNP) were screen-printed on YSZ substrate using ethanol and alpha-terpineol solvents. The structure and morphology of LSM-YSZ thin films using two solvents were compared. Results showed that both solvents produced a rhombohedral LSM and cubic YSZ thin films and the use of a-terpineol solvent with higher solid content produced a desired uniform and porous morphology with homogenous pore distribution as revealed by XRD and SEM morphological results.
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油墨溶剂对固体氧化物电化学电池用YSZ基板上LSM-YSZ薄膜丝网印刷制备及形貌的影响
丝网印刷是一种廉价而简单的薄膜沉积技术,用于制造能源器件,特别是固体氧化物电化学电池(soc)。在本研究中,采用丝网印刷的方法在YSZ电解液上沉积了一种极具应用前景的元件材料LSM-YSZ。具体而言,本研究旨在探讨丝网印刷中使用的溶剂和不同油墨配方对沉积膜质量的影响。采用甘氨酸-硝酸燃烧法(GNP)合成了LSM-YSZ前驱体粉末,采用乙醇和-松油醇溶剂在YSZ底物上进行了丝网印刷。比较了两种溶剂制备的LSM-YSZ薄膜的结构和形貌。结果表明,两种溶剂均能制备出菱面体LSM和立方体YSZ薄膜,采用固含量较高的a-松油醇溶剂制备出了理想的均匀多孔形貌,XRD和SEM形貌分析结果显示其孔隙分布均匀。
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