Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips during Remelting

Pınar YÖRÜK, Mertol GÖKELMA
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Abstract

Magnesium is one of the metals listed in European Union’s critical raw materials list. Primary production of magnesium is a high energy demanding process which raised the necessity of recycling the magnesium alloys in an efficient way. Remelting those scraps under a salt flux consist of chlorides (NaCl, KCl, and MgCl2) and fluorides (CaF2) is a common process however, different alloys might behave differently when it comes to salt-metal-metal oxide interactions. Furthermore, the condition of the salt flux such as dry-mixed or pre-melted (fused) affects the coagulation and metal yield. This work presents results on the effect of CaF2 concentration and pre-melting the salt flux on metal yield during remelting of chips. A yield up to 75% was observed in the case of remelting of chips under a fused salt flux with 5.5% CaF2 concentration.
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CaF2添加量对AZ63镁片重熔产率的影响
镁是被列入欧盟关键原材料清单的金属之一。镁的初级生产是一个高耗能的过程,这就提出了有效回收镁合金的必要性。在由氯化物(NaCl, KCl和MgCl2)和氟化物(CaF2)组成的盐助熔剂下重熔这些废料是一个常见的过程,然而,当涉及到盐-金属-金属氧化物相互作用时,不同的合金可能表现不同。此外,盐通量的条件,如干混或预熔(熔融)影响混凝和金属收率。本文介绍了在切屑重熔过程中,CaF2浓度和预熔盐通量对金属产率的影响。在CaF2浓度为5.5%的熔盐熔剂下,薄片的重熔率可达75%。
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