Investigating the Effect of Thermal Annealing and Changing the Concentration of GO in GO/PVA Nanocomposites on Their Structural, Electrical, and Optical Properties

IF 2.8 Q2 ENGINEERING, CHEMICAL ChemEngineering Pub Date : 2023-10-04 DOI:10.3390/chemengineering7050092
Lala Gahramanli, Mustafa Muradov, Goncha Eyvazova, Mahammad Baghir Baghirov, Sevinj Mammadyarova, Gunel Aliyeva, Elman Hajiyev, Faig Mammadov, Stefano Bellucci
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Abstract

The present research involves producing graphene oxide (GO) using the Hummers method, generating a composite using GO and PVA, and analyzing these composites’ structural and optical characteristics. PVA and GO were used in varied percentages to deal with the issue of how the features of GO/PVA alter depending on concentration. The impact of thermal annealing on the structure and optical characteristics of GO/PVA materials at various concentrations were also investigated. UV-VIS was used to investigate the band gap value of GO/PVA composites. The band gap value changed due to an increase in the concentration of GO in the composites in the PVA and the impact of thermal annealing. The band gap value, specific resistance, and dielectric constant were all found to be well controlled by varying the thermal annealing temperature and the concentration of GO in this case. Differential Scanning Calorimetry (DSC) and thermogravimetric analysis (TGA) were performed on pure PVA and GO/PVA samples in various percentages of GO in order to examine the effect of temperature on the physical properties of (n = 1, 2, 3, 5, 20%) nGO%/PVA nanocomposites. Thermal stability increased as the fraction of GO in the PVA polymer matrix increased.
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研究热处理和改变氧化石墨烯/聚乙烯醇纳米复合材料中氧化石墨烯的浓度对其结构、电学和光学性能的影响
目前的研究包括使用Hummers方法生产氧化石墨烯(GO),使用GO和PVA生成复合材料,并分析这些复合材料的结构和光学特性。采用不同百分比的PVA和GO来处理GO/PVA的特性如何随浓度变化的问题。研究了热处理对不同浓度氧化石墨烯/聚乙烯醇材料结构和光学特性的影响。利用紫外可见光谱(UV-VIS)研究了氧化石墨烯/聚乙烯醇复合材料的带隙值。带隙值的变化是由于复合材料中氧化石墨烯浓度的增加和热处理的影响。在这种情况下,通过改变热退火温度和氧化石墨烯的浓度,可以很好地控制带隙值、比电阻和介电常数。采用差示扫描量热法(DSC)和热重分析(TGA)对不同氧化石墨烯含量的纯PVA和氧化石墨烯/PVA样品进行了研究,考察了温度对(n = 1,2,3,5,20 %) nGO%/PVA纳米复合材料物理性能的影响。随着PVA聚合物基体中氧化石墨烯含量的增加,热稳定性提高。
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来源期刊
ChemEngineering
ChemEngineering Engineering-Engineering (all)
CiteScore
4.00
自引率
4.00%
发文量
88
审稿时长
11 weeks
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