Tungsten and molybdenum based polyoxometalates for photo and electrocatalytic carbon dioxide conversion – A critical review

IF 9.1 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Progress in Solid State Chemistry Pub Date : 2023-12-01 DOI:10.1016/j.progsolidstchem.2023.100430

Shivangini Bhatt , Sumit Saha

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Abstract

Today, carbon dioxide (CO₂) is one of the most pervasive greenhouse gases in the atmosphere, mainly because of the burning of fossil fuels. The carbon dioxide reduction reaction by photocatalysis and electrocatalysis is one approach that holds a lot of promise for easing the global crisis on the environmental and energy fronts. Developing and constructing high-performance photo- and electrocatalysts is a challenge that is being studied. The class of anionic metal-oxo clusters known as polyoxometalates (POMs) brings diverse and interesting chemical and physical characteristics that can be modified easily. The studies reveal that POMs are emerging to be distinctive photo/electrocatalysts for these reactions because of their unmatched advantages, like thermal and redox stability, light-absorbing capacity, quasi-semiconductor properties, etc. Numerous studies have demonstrated the capability of tungsten and molybdenum-based photo- and electrocatalysts for CO₂ reduction and conversion into value-added products. This review has covered the most recent developments in tungsten and molybdenum-based POMs that convert CO₂ into multiple products (CO, H₂, HCOOH, HCHO, CH₃OH, etc.). Perspectives for designing and constructing different kinds of POM-based catalytic systems have been offered.

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光催化和电催化二氧化碳转化用钨和钼基多金属氧酸盐。综述

今天，二氧化碳(CO2)是大气中最普遍的温室气体之一，主要是因为化石燃料的燃烧。光催化和电催化的二氧化碳还原反应是一种很有希望缓解全球环境和能源危机的方法。开发和构建高性能的光电催化剂是目前研究的一个挑战。阴离子金属-氧簇被称为多金属氧酸盐(pom)，具有多种有趣的化学和物理特性，易于修饰。这些研究表明，由于其无可比拟的优势，如热稳定性和氧化还原稳定性、光吸收能力、准半导体性质等，pom正在成为这些反应的独特光/电催化剂。许多研究已经证明了钨和钼基光催化剂和电催化剂在二氧化碳还原和转化为增值产品方面的能力。本文综述了钨基和钼基pom的最新进展，这些pom可以将CO2转化为多种产物(CO, H2, HCOOH, HCHO, CH3OH等)。为设计和构建不同类型的pom基催化体系提供了前景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Progress in Solid State Chemistry 化学-无机化学与核化学

CiteScore

14.10

自引率

3.30%

发文量

期刊介绍： Progress in Solid State Chemistry offers critical reviews and specialized articles written by leading experts in the field, providing a comprehensive view of solid-state chemistry. It addresses the challenge of dispersed literature by offering up-to-date assessments of research progress and recent developments. Emphasis is placed on the relationship between physical properties and structural chemistry, particularly imperfections like vacancies and dislocations. The reviews published in Progress in Solid State Chemistry emphasize critical evaluation of the field, along with indications of current problems and future directions. Papers are not intended to be bibliographic in nature but rather to inform a broad range of readers in an inherently multidisciplinary field by providing expert treatises oriented both towards specialists in different areas of the solid state and towards nonspecialists. The authorship is international, and the subject matter will be of interest to chemists, materials scientists, physicists, metallurgists, crystallographers, ceramists, and engineers interested in the solid state.