Dynamic and Relaxation of PEG polymer Chain Segment for Phase Change Materials (PCMs)

IF 4.6 Q1 OPTICS Journal of Physics-Photonics Pub Date : 2023-11-01 DOI:10.1088/1742-6596/2623/1/012020
N A Fauziyah, None Sakinah, W Rachma, S Paratapa, D S Perwitasaric, P C Wardhani, E N Hidayah
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Abstract

Abstract This work’s most notable memory concept for next-generation novels was a reversible phase shift in a substance called phase change materials (PCMs). Here, a polyethylene glycol (PEG) polymer relaxation study employing DMA will be conducted to investigate the qualities of PCMs as superior materials. Through the method of wet mixing, PEG polymer with reinforcement made of silica was synthesized. The variation of silica xerogel was a composition of up to 20% silica xerogel. Adding silica is quite good in reducing the loss factor up to 50 MPa at the addition of 20% silica xerogel. This condition was due to the bonds formed in the polymer chain causing shrinkage and flexibility of composites. Due to the addition of silica xerogel as filler, we can study the relaxation behavior and loss factor of a material using DMA and learn more about its viscoelastic characteristics, including its capacity to absorb vibrations, resistance to impacts, and overall mechanical performance at various temperatures. Relaxation was frequently used to describe phase change materials (PCMs), especially when discussing their capacity to store thermal energy. The release or absorption of thermal energy by a PCM during its phase transition was referred to as the relaxation process.
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相变材料(PCMs)中聚乙二醇聚合物链段的动态与弛豫
这项工作最显著的记忆概念的下一代小说是可逆相移的物质称为相变材料(PCMs)。本文将采用DMA进行聚乙二醇(PEG)聚合物弛豫研究,以研究聚乙二醇作为优越材料的质量。通过湿法混合,合成了以二氧化硅为增强材料的聚乙二醇聚合物。变异的二氧化硅干凝胶是由高达20%的二氧化硅干凝胶组成的。添加二氧化硅可以很好地降低损失因子,在添加20%二氧化硅干凝胶时可降低到50 MPa。这种情况是由于聚合物链中形成的键引起复合材料的收缩和柔韧性。由于添加了二氧化硅凝胶作为填料,我们可以使用DMA研究材料的松弛行为和损失因子,并了解更多关于其粘弹性特性的信息,包括其吸收振动的能力,抗冲击能力以及在不同温度下的整体机械性能。弛豫经常被用来描述相变材料,特别是在讨论它们储存热能的能力时。相变过程中热能的释放或吸收称为弛豫过程。
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来源期刊
CiteScore
10.70
自引率
0.00%
发文量
27
审稿时长
12 weeks
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