High-resolution reconstruction of infiltration in the Southern Cook Islands based on trace elements in speleothems

IF 1.7 3区 地球科学 Q3 GEOGRAPHY, PHYSICAL Quaternary Research Pub Date : 2023-10-02 DOI:10.1017/qua.2023.51
Mohammadali Faraji, Andrea Borsato, Silvia Frisia, Adam Hartland, John C. Hellstrom, Alan Greig
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Abstract

Abstract This study utilizes speleothem trace elements as climate proxies to reconstruct hydroclimate variability over approximately 350 years in the Southern Cook Islands. Stalagmites Pu17 and Pu4 from Pouatea cave were analyzed using high-resolution LA-ICP-MS for trace elements (Mg, Na, Sr, P, U, Y). By monitoring cave dripwater and conducting regression analysis, we found that Mg, Sr, and Na in Pouatea dripwater mostly originated from marine aerosols, while Sr and Ba were primarily from bedrock, with additional Ba coming from marine aerosols and weathered oceanic basalt leaching. Mg was identified as the most reliable element for hydroclimate reconstruction due to its predominantly marine aerosol origin. Infiltration, via dilution of marine aerosols and bedrock inputs, was identified as the main driver of trace element variations in Pouatea at a seasonal scale. Transfer functions were established between each trace element and effective infiltration was calculated, with Mg showing the strongest correlation. The reconstructed infiltration data were compared with climate indices, showing an overarching role of the SPCZ and ENSO in controlling rainfall in the South Pacific. This research demonstrates the potential of speleothem trace elements for paleohydroclimate reconstructions, improving understanding of rainfall variability in the climatically vulnerable South Pacific Islands over the past millennia.
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基于洞穴中微量元素的南库克群岛浸润的高分辨率重建
摘要:本研究利用洞穴中微量元素作为气候指标,重建了南库克群岛近350年来的水文气候变化。采用高分辨率LA-ICP-MS对Pouatea洞穴石笋Pu17和Pu4进行微量元素(Mg、Na、Sr、P、U、Y)分析。通过对洞穴滴水的监测和回归分析,发现Pouatea洞穴滴水中Mg、Sr和Na主要来源于海相气溶胶,Sr和Ba主要来源于基岩,Ba来源于海相气溶胶和海洋风化玄武岩淋滤。由于Mg主要来源于海洋气溶胶,因此被认为是水文气候重建最可靠的元素。通过稀释海洋气溶胶和基岩输入的入渗,被确定为Pouatea微量元素季节性变化的主要驱动因素。建立了各微量元素与有效入渗之间的传递函数,其中Mg的相关性最强。通过与气候指数的比较,发现SPCZ和ENSO在控制南太平洋降水中起着重要作用。这项研究证明了洞穴微量元素在古水文气候重建中的潜力,提高了对过去千年气候脆弱的南太平洋岛屿降雨变化的理解。
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来源期刊
Quaternary Research
Quaternary Research 地学-地球科学综合
CiteScore
4.70
自引率
8.70%
发文量
57
审稿时长
3 months
期刊介绍: Quaternary Research is an international journal devoted to the advancement of the interdisciplinary understanding of the Quaternary Period. We aim to publish articles of broad interest with relevance to more than one discipline, and that constitute a significant new contribution to Quaternary science. The journal’s scope is global, building on its nearly 50-year history in advancing the understanding of earth and human history through interdisciplinary study of the last 2.6 million years.
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