Synthesis, structure and property investigation of a three-dimensional Zn (II) metal–organic frameworks

IF 1.2 4区材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Functional Materials Letters Pub Date : 2023-10-17 DOI:10.1142/s1793604723500200

Cong-Cong Jiang, Dong-Xin Xu, Pei-Xin Bai, Yong-Xiang Wang, Cheng Zhang, Jun Wang, Shi-Xin Sun

引用次数: 0

Abstract

A new three-dimensional Zn(II) complex named [Zn(1,3-BMIB)(TBIP)⋅2H2O] n (1) (containning 1,3-BMIB 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene, H 2 TBIP=5-tert-butyl isophthalic acid) had been prepared by hydrothermal synthesis. Systematic structural characterization, especially the single crystal X-ray diffraction method, discreetly reveal the complex 1 exhibits three-dimensional (3D) framework with CdSO 4 topology. The 3D crystrals 1 display solid-state fluorescence behavior at room temperature, indicating the potential of the candidate materials for absorbing and using visible light. The photocatalytic properties of compound 1 were estimated through the model photodecomposition dye pollutants using methylene blue (MB) and rhodamine B (RhB) under visible light irradiation.

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三维Zn (II)金属-有机骨架的合成、结构与性能研究

采用水热法合成了一种新的三维Zn(II)配合物[Zn(1,3- bmib)(TBIP)⋅2H2O] n(1)(含1,3- bmib 1,3-双(2-甲基- 1h -咪唑-1-基)苯，H2 TBIP=5-叔丁基异苯二甲酸)。系统的结构表征，特别是单晶x射线衍射方法，谨慎地揭示了配合物1具有cdso4拓扑结构的三维(3D)框架。三维晶体1在室温下显示固态荧光行为，表明候选材料吸收和利用可见光的潜力。通过亚甲基蓝(MB)和罗丹明B (RhB)在可见光照射下的光分解染料污染物模型，估计了化合物1的光催化性能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Functional Materials Letters 工程技术-材料科学：综合

CiteScore

2.40

自引率

7.70%

发文量

审稿时长

1.9 months

期刊介绍： Functional Materials Letters is an international peer-reviewed scientific journal for original contributions to research on the synthesis, behavior and characterization of functional materials. The journal seeks to provide a rapid forum for the communication of novel research of high quality and with an interdisciplinary flavor. The journal is an ideal forum for communication amongst materials scientists and engineers, chemists and chemical engineers, and physicists in the dynamic fields associated with functional materials. Functional materials are designed to make use of their natural or engineered functionalities to respond to changes in electrical and magnetic fields, physical and chemical environment, etc. These design considerations are fundamentally different to those relevant for structural materials and are the focus of this journal. Functional materials play an increasingly important role in the development of the field of materials science and engineering. The scope of the journal covers theoretical and experimental studies of functional materials, characterization and new applications-related research on functional materials in macro-, micro- and nano-scale science and engineering. Among the topics covered are ferroelectric, multiferroic, ferromagnetic, magneto-optical, optoelectric, thermoelectric, energy conversion and energy storage, sustainable energy and shape memory materials.