Carbides of transition metals: Properties, application and production. Review. Part 2. Chromium and zirconium carbides

Abstract

The properties, application, and methods for producing chromium and zirconium carbides are considered. These carbides are oxygen-free refractory metal-like compounds. As a result, they are characterized by high values of thermal and electrical conductivity. Their hardness is relatively high. Chromium and zirconium carbides exhibit significant chemical resistance in aggressive environments. For these reasons, they have found application in modern technology. Chromium carbide is used mainly as component of surfacing mixtures to create protective coatings that resist intensive abrasive wear, including at elevated temperatures (up to 800 °C) in oxidizing environments. This compound is also used in the manufacture of tungsten-free hard alloys and carbide steels. Chromium carbide, along with vanadium carbide, is used as a grain growth inhibitor in WC – Co hard alloys. Powdered zirconium carbide can be used to polish the surface of items made of ferrous and non-ferrous metals. The properties of refractory compounds depend on the content of impurities and dispersion (particle size). To solve a specific problem associated with the use of refractory compounds, it is important to choose the right method for their preparation, to determine the permissible content of impurities in the initial components. This leads to the existence of different methods for the synthesis of carbides. The main methods for their preparation are: synthesis from simple substances (metals and carbon), metallothermal and carbothermal reduction. Plasma-chemical synthesis (vapor-gas phase deposition) is also used to obtain carbide nanopowders. A characteristic is given to each of these methods. Information on the possible mechanism of the processes of carbothermal synthesis is presented.