Magnetic nanoparticles supported copper (II) complex: Fe3O4@DABA-PQ-CuCl2 nanocomposite as an active magnetically recoverable catalyst for preparation of diaryl (aryl-heterocyclic) selenides

IF 2.1 3区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Sulfur Chemistry Pub Date : 2024-01-01 DOI:10.1080/17415993.2023.2255713
Wei Li , Wenjing Xu , Jinlong Yan , Li Yan Zhang
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Abstract

During the last few years, research on new approaches for the synthesis of diaryl selenides containing heterocyclic compounds (Heterocyclic-Selenide-Aryl derivatives) has gained special importance among chemists. These compounds are very valuable from pharmaceutical and pharmacological points of view, and several biological properties such as anti-cancer and antitumor properties have been reported about them. In this research, we presented an ecofriendly and efficient method to prepare diaryl selenides containing heterocyclic compounds through one-pot three-component reactions of heterocyclic compounds with aryl iodides and selenium catalyzed by Fe3O4@DABA-PQ-CuCl2 nanocomposite in PEG as solvent under thermal conditions. Fe3O4@DABA-PQ-CuCl2 nanocomposite was successfully fabricated by using simple method and was fully identified by several spectroscopic techniques. The use of nanocatalysts synthesized in this work has the following advantages over the catalysts reported in the articles: low toxicity, easy storage, transportation, weighing and application, easy preparation of catalyst from cheap and available raw materials, high activity of catalyst due to increased surface area, stability in solvents and at high temperatures, high selectivity, recyclability and reuse of catalyst.

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磁性纳米颗粒支撑的铜(II)络合物:作为制备二芳基(芳基-杂环)硒化物的活性磁性可回收催化剂的 Fe3O4@DABA-PQ-CuCl2 纳米复合材料
在过去几年中,化学家们对合成含有杂环化合物(杂环硒化芳基衍生物)的二芳基硒化物的新方法进行了特别重要的研究。从药物学和药理学的角度来看,这些化合物非常有价值,而且已有关于它们的一些生物特性(如抗癌和抗肿瘤特性)的报道。在本研究中,我们提出了一种环保、高效的制备含杂环化合物的二芳基硒化物的方法,该方法是在热条件下,以 PEG 为溶剂,在 Fe3O4@DABA-PQ-CuCl2 纳米复合材料的催化下,通过杂环化合物与芳基碘化物和硒的单锅三组分反应制备二芳基硒化物。采用简单的方法成功制备了Fe3O4@DABA-PQ-CuCl2纳米复合材料,并通过多种光谱技术进行了充分鉴定。与其他文章报道的催化剂相比,本研究合成的纳米催化剂具有以下优点:低毒性,易于储存、运输、称重和应用;易于用廉价和可获得的原材料制备催化剂;由于表面积增大,催化剂活性高;在溶剂和高温条件下稳定;高选择性;催化剂可回收和重复使用。
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来源期刊
Journal of Sulfur Chemistry
Journal of Sulfur Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.10
自引率
9.10%
发文量
38
审稿时长
6-12 weeks
期刊介绍: The Journal of Sulfur Chemistry is an international journal for the dissemination of scientific results in the rapidly expanding realm of sulfur chemistry. The journal publishes high quality reviews, full papers and communications in the following areas: organic and inorganic chemistry, industrial chemistry, materials and polymer chemistry, biological chemistry and interdisciplinary studies directly related to sulfur science. Papers outlining theoretical, physical, mechanistic or synthetic studies pertaining to sulfur chemistry are welcome. Hence the target audience is made up of academic and industrial chemists with peripheral or focused interests in sulfur chemistry. Manuscripts that truly define the aims of the journal include, but are not limited to, those that offer: a) innovative use of sulfur reagents; b) new synthetic approaches to sulfur-containing biomolecules, materials or organic and organometallic compounds; c) theoretical and physical studies that facilitate the understanding of sulfur structure, bonding or reactivity; d) catalytic, selective, synthetically useful or noteworthy transformations of sulfur containing molecules; e) industrial applications of sulfur chemistry; f) unique sulfur atom or molecule involvement in interfacial phenomena; g) descriptions of solid phase or combinatorial methods involving sulfur containing substrates. Submissions pertaining to related atoms such as selenium and tellurium are also welcome. Articles offering routine heterocycle formation through established reactions of sulfur containing substrates are outside the scope of the journal.
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