Takeshi Matsuda, Shinichi Furuya, Rie Kaneko, Koji Fushimi
{"title":"Corrosion protection behaviour of electrogalvanised steel sheet by tetravalent vanadium ion","authors":"Takeshi Matsuda, Shinichi Furuya, Rie Kaneko, Koji Fushimi","doi":"10.1080/00202967.2023.2225285","DOIUrl":null,"url":null,"abstract":"The corrosion protection behaviour of electrogalvanised steel sheets (EG) by the tetravalent vanadium ion was investigated. Immersion of the bare EG in a NaCl solution revealed that the addition of vanadium(IV) oxide sulphate to the solution led to a transition of the open circuit potential to less noble and the formation of vanadium oxides on the EG surface. The oxide layer included not only vanadium(III) oxides but also a small amount of ZnO, indicating that Zn on the EG surface was oxidised while the vanadium(IV) species was reduced to the vanadium(III) species. The corrosion current density of the EG with the adhering vanadium(III) species was one order of magnitude smaller than that of the bare EG, clearly suggesting that zinc corrosion was reduced by suppressing the reduction reaction of dissolved oxygen. The vanadium(IV) species could be a candidate as a self-healing inhibitor for chromate-free coating technologies by controlling the coupling of Zn oxidation and vanadium(IV) reduction.","PeriodicalId":23268,"journal":{"name":"Transactions of The Institute of Metal Finishing","volume":"37 1","pages":"0"},"PeriodicalIF":1.2000,"publicationDate":"2023-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Institute of Metal Finishing","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/00202967.2023.2225285","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0
Abstract
The corrosion protection behaviour of electrogalvanised steel sheets (EG) by the tetravalent vanadium ion was investigated. Immersion of the bare EG in a NaCl solution revealed that the addition of vanadium(IV) oxide sulphate to the solution led to a transition of the open circuit potential to less noble and the formation of vanadium oxides on the EG surface. The oxide layer included not only vanadium(III) oxides but also a small amount of ZnO, indicating that Zn on the EG surface was oxidised while the vanadium(IV) species was reduced to the vanadium(III) species. The corrosion current density of the EG with the adhering vanadium(III) species was one order of magnitude smaller than that of the bare EG, clearly suggesting that zinc corrosion was reduced by suppressing the reduction reaction of dissolved oxygen. The vanadium(IV) species could be a candidate as a self-healing inhibitor for chromate-free coating technologies by controlling the coupling of Zn oxidation and vanadium(IV) reduction.
期刊介绍：
Transactions of the Institute of Metal Finishing provides international peer-reviewed coverage of all aspects of surface finishing and surface engineering, from fundamental research to in-service applications. The coverage is principally concerned with the application of surface engineering and coating technologies to enhance the properties of engineering components and assemblies. These techniques include electroplating and electroless plating and their pre- and post-treatments, thus embracing all cleaning pickling and chemical conversion processes, and also complementary processes such as anodising. Increasingly, other processes are becoming important particularly regarding surface profile, texture, opacity, contact integrity, etc.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
