THE EFFECT OF BLENDING RATIO ON BIODIESEL PROPERTIES, EMISSIONS AND ENGINE PERFORMANCE

Mohd Affandi Mohd Ali, Liyana Amer Shah, Nurul Hidayah Ghazali
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Abstract

This work presents the effects of biodiesel blending on its properties, emissions, and performance. The rubber seed oil (RSO) and waste cooking oil (WCO)-based biodiesel were prepared using a transesterification method in the presence of a heterogeneous catalyst. Several formulations were derived from two types of biodiesels (RSO and WCO) and tested according to the ASTM D6751 specification for acid value, free fatty acid (FFA), kinematic viscosity, pour point, cloud point, density, and calorific value. For the WCO-based biodiesel, the best blend was WCO B5, with properties closely matching those of petrodiesel. Significantly, the formulations with higher WCO content (e.g., B10 and above) suffered from serious drops (above 8%) in calorific value. In contrast, the RSO diesel blend showed less than 5% drops in calorific value for formulations up to a 20% biodiesel blend (B20). In addition, an indiscernible difference was obtained between the WCO B5, RSO B5, and petrodiesel in terms of engine power, torque, and CO2 emissions, although the RSO B5 did produce less NOx (158 ppm) than both the WCO B5 (390 ppm) and the petrodiesel (220 ppm). The results showed that blending of WCO and RSO with petrodiesel up to 10%, i.e., B10, is practically applicable for diesel cars with power reduction less than 10%.
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混合比例对生物柴油性能、排放和发动机性能的影响
本文介绍了混合生物柴油对其特性、排放和性能的影响。采用多相催化剂催化酯交换法制备了橡胶籽油(RSO)和废食用油(WCO)基生物柴油。从两种类型的生物柴油(RSO和WCO)衍生出几种配方,并根据ASTM D6751规范进行酸值、游离脂肪酸(FFA)、运动粘度、倾点、浊点、密度和热值测试。以WCO为原料制备生物柴油的最佳混合料为WCO B5,其性能与石油柴油基本一致。值得注意的是,WCO含量较高(如B10及以上)的配方发热量严重下降(超过8%)。相比之下,RSO柴油混合物的热值下降不到5%,配方高达20%的生物柴油混合物(B20)。此外,在发动机功率、扭矩和二氧化碳排放方面,WCO B5、RSO B5和汽油柴油之间存在着难以察觉的差异,尽管RSO B5产生的氮氧化物(158 ppm)确实比WCO B5 (390 ppm)和汽油柴油(220 ppm)少。结果表明,WCO和RSO与10%的汽油柴油(即B10)混合,实际适用于减排量小于10%的柴油车。
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