Influence of Crystal Structure on the Set of Physicomechanical Characteristics of Composite Materials Based on Ultra-High Molecular Weight Polyethylene

IF 1 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series B Pub Date : 2023-10-29 DOI:10.1134/S1560090423701221
A. S. Zabolotnov, S. S. Gostev, I. A. Maklakova, A. V. Bakirov, L. A. Novokshonova, A.A. Kiyasov
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Abstract

Using the polymerization filling technique, composite materials have been obtained based on ultra-high molecular weight PE and fillers of platelike (graphene or graphite nanoplatelets) and spherical (silica) types. The tensile stress–strain characteristics of samples obtained using different pressing modes have been examined. It has been revealed that the cooling rate of the samples during pressing affects the values of ultimate tensile strength and modulus of elasticity in tension. The characteristics of composites processed at a low cooling rate (10 K/h) are 30% higher than those of the samples obtained at a high cooling rate (10 K/min). Using DSC, DMA, and X-ray diffraction methods, it has been shown that the way of cooling affects the crystallite size of compressed samples of composite materials.

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晶体结构对基于超高分子量聚乙烯的复合材料物理力学特性的影响
利用聚合填充技术,获得了基于超高分子量聚乙烯和板状(石墨烯或石墨纳米片)及球状(二氧化硅)填充物的复合材料。对采用不同压制模式获得的样品的拉伸应力-应变特性进行了研究。结果表明,压制过程中样品的冷却速度会影响拉伸过程中的极限拉伸强度和弹性模量值。以低冷却速率(10 K/h)加工的复合材料的特性比以高冷却速率(10 K/min)加工的样品高出 30%。使用 DSC、DMA 和 X 射线衍射方法表明,冷却方式会影响复合材料压缩样品的晶粒大小。
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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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