Preliminary assessment of road dust from Portuguese motorways: chemical profile, health risks, and ecotoxicological screening

IF 2.9 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Air Quality Atmosphere and Health Pub Date : 2023-09-21 DOI:10.1007/s11869-023-01424-y
Ismael Casotti Rienda, Teresa Nunes, Fulvio Amato, Franco Lucarelli, Nora Kováts, Katalin Hubai, Célia A. Alves
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Abstract

Among non-exhaust emissions, road dust resuspension represents a rather important contribution to particulate matter in urban areas. This study aimed to achieve a chemical characterisation of road dust particulate matter (PM10) on two motorway sections, one rural and one urban, and to explore the related health and ecotoxicological risks. Measured PM10 dust loadings reached very low levels (0.66–1.49 mg m-2) compared to equivalent studies in other road environments in Portugal and other countries. Emission factors ranged from 33 to 62 mg veh−1 km−1. The carbonaceous content represented 14% of the total PM10 mass, whereas the highest contribution to the mass was given by mineral matter. Elements such as Si, Al, Ca, Fe and K accounted for almost three quarters of the total element mass for all samples, whilst Cu and Zn, mostly associated with brake and tyre wear, were the most enriched elements in relation to the soil composition. Nonetheless, Ti and Zr presented the highest non-carcinogenic risks for human health. Despite the low amounts of particulate matter in the aqueous solution, the ecotoxicological screening with the Aliivibrio fisheri bioluminescence inhibition bioassay allowed to classify the samples as toxic.

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葡萄牙高速公路道路粉尘的初步评估:化学特征、健康风险和生态毒理学筛选
在非尾气排放中,道路粉尘再悬浮对城市颗粒物的贡献相当大。本研究的目的是实现道路粉尘颗粒物质(PM 10)的化学特征在两个高速公路路段,一个农村和一个城市,并探讨相关的健康和生态毒理学风险。与葡萄牙和其他国家在其他道路环境中进行的等效研究相比,测量到的pm10粉尘负荷达到了非常低的水平(0.66-1.49 mg m -2)。排放因子范围为33 ~ 62 mg veh−1 km−1。碳质含量占PM 10总质量的14%,而矿物对质量的贡献最大。Si、Al、Ca、Fe和K等元素几乎占所有样品总元素质量的四分之三,而Cu和Zn是土壤成分中最富集的元素,主要与刹车和轮胎磨损有关。然而,钛和锆对人类健康的非致癌风险最高。尽管水溶液中颗粒物质的含量很低,但用鱼弧菌生物发光抑制生物测定法进行的生态毒理学筛选允许将样品分类为有毒。
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来源期刊
Air Quality Atmosphere and Health
Air Quality Atmosphere and Health ENVIRONMENTAL SCIENCES-
CiteScore
8.80
自引率
2.00%
发文量
146
审稿时长
>12 weeks
期刊介绍: Air Quality, Atmosphere, and Health is a multidisciplinary journal which, by its very name, illustrates the broad range of work it publishes and which focuses on atmospheric consequences of human activities and their implications for human and ecological health. It offers research papers, critical literature reviews and commentaries, as well as special issues devoted to topical subjects or themes. International in scope, the journal presents papers that inform and stimulate a global readership, as the topic addressed are global in their import. Consequently, we do not encourage submission of papers involving local data that relate to local problems. Unless they demonstrate wide applicability, these are better submitted to national or regional journals. Air Quality, Atmosphere & Health addresses such topics as acid precipitation; airborne particulate matter; air quality monitoring and management; exposure assessment; risk assessment; indoor air quality; atmospheric chemistry; atmospheric modeling and prediction; air pollution climatology; climate change and air quality; air pollution measurement; atmospheric impact assessment; forest-fire emissions; atmospheric science; greenhouse gases; health and ecological effects; clean air technology; regional and global change and satellite measurements. This journal benefits a diverse audience of researchers, public health officials and policy makers addressing problems that call for solutions based in evidence from atmospheric and exposure assessment scientists, epidemiologists, and risk assessors. Publication in the journal affords the opportunity to reach beyond defined disciplinary niches to this broader readership.
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