Phase transitions in chrome

Oleksandr Shevcenko
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Abstract

In astronautics, stainless steel is widely used for the manufacture of spacecraft. Rocket fuel tanks are now made of stainless steel. In order for steel to be stainless, for example, grades 08X13 and 12X13, it must contain up to 13% chromium. In pure chromium and its alloys, phase transitions occur under temperature fluctuations and mechanical loads, during which the plastic, strength, and magnetic characteristics of steel alloys change. The article describes distinguishes between phase transformations of the 1st and 2nd kind in chromium and the inconsistency in the definition of the type of transition by different authors. The change in the form of the crystal lattice during the transition from an antiferromagnet to a paramagnet at the Neel point TN = 38 85 °C, is described. An analysis of the relationship between the type of phase transition and the type of symmetry is given. An explanation is given for the difficulties in studying phase transitions in chromium due to the imperfection of the model of the electronic configuration in the 3d layer of the chromium atom.
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铬的相变
在航天领域,不锈钢被广泛用于制造航天器。火箭燃料箱现在是由不锈钢制成的。为了使钢成为不锈钢,例如,牌号08X13和12X13,它必须含有高达13%的铬。在纯铬及其合金中,在温度波动和机械载荷下会发生相变,在此期间钢合金的塑性、强度和磁性会发生变化。本文描述了铬中第一类和第二类相变的区别,以及不同作者对转变类型定义的不一致。描述了在Neel点TN = 38 - 85℃时,由反铁磁体向顺磁体转变过程中晶格形态的变化。分析了相变类型与对称类型之间的关系。解释了由于铬原子三维层电子组态模型的不完善而导致研究铬相变的困难。
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