Thermal Hydraulics Simulation of a Water Spray System for a Cooling Fluid Catalytic Cracking (FCC) Regenerator

Alon Davidy
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Abstract

Olefins are crucial building blocks for petrochemical industry, serving as raw materials for the production of various products such as plastics, synthetic fibers, detergents, solvents, and other chemicals. In FCC, heavy petroleum feedstocks are injected into a catalytic cracking unit, where they are mixed with a catalyst. The catalyst aids in breaking down the large hydrocarbon molecules into smaller fragments, including olefins like Propylene and Ethylene. These polymerization reactions occur at high temperatures. They demand that heat removal occurs as quickly as possible in order to control the reactor temperature and to avoid “hot spots” in the Regenerator or localized oxidation reactions (and to avoid creep rupture of the regenerator steel cladding). The cooling of the regenerator cladding surface can be achieved by impinging water droplets (spray), ejected from a spray nozzle. Spray cooling can provide uniform cooling and handle high heat fluxes in both a single phase and two phases. This research provides a thermal hydraulic design of regenerator spray cooling systems. In the framework of this research, Fire Dynamics Simulator (FDS) software was applied in order to simulate the temperature field and the water vapor mass fraction. A COMSOL Multiphysics finite element code was used in order to calculate the temperature field inside the regenerator cladding. The calculated surface temperatures and heat transfer convective coefficient, obtained using FDS software, were validated successfully against COMSOL numerical results and previous results in the literature. The numerical simulations were carried out for two cases. The first case was carried out at a distance of 0.5 m, and the second case was carried out at a distance of 0.2 m. A grid sensitivity study was carried out on the FDS model. Numerical integrations were carried out over time in order to calculate the average temperatures. The difference between these four average temperatures, calculated by applying different grids, is less than 7.4%. The calculated surface temperatures and heat transfer convective coefficient were validated successfully against COMSOL numerical results and previous research. It was shown that the calculated temperatures decrease in the second case. The water spray system managed to cool the steel wall more effectively as the water spray system approaches the steel cladding.
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催化裂化(FCC)蓄热器喷水系统的热液压仿真
烯烃是石油化工行业的重要组成部分,是生产各种产品的原料,如塑料、合成纤维、洗涤剂、溶剂和其他化学品。在催化裂化中,重质石油原料被注入催化裂化装置,在那里它们与催化剂混合。催化剂有助于将大的碳氢化合物分子分解成更小的碎片,包括像丙烯和乙烯这样的烯烃。这些聚合反应发生在高温下。他们要求尽可能快地进行散热,以控制反应堆温度,避免再生器中的“热点”或局部氧化反应(并避免再生器钢包层的蠕变破裂)。蓄热器包层表面的冷却可以通过从喷嘴喷射的水滴(喷雾)来实现。喷雾冷却既可以提供均匀的冷却,也可以处理单相和两相的高热流。本研究提供了蓄热喷雾冷却系统的热水力设计。在本研究的框架下,应用Fire Dynamics Simulator (FDS)软件对温度场和水蒸气质量分数进行模拟。采用COMSOL多物理场有限元程序对蓄热器包层内的温度场进行了计算。利用FDS软件计算得到的表面温度和换热对流系数,与COMSOL数值结果和文献中已有的结果进行了验证。对两种情况进行了数值模拟。第一个病例在0.5 m的距离处进行,第二个病例在0.2 m的距离处进行。对FDS模型进行了网格敏感性研究。为了计算平均温度,在一段时间内进行了数值积分。通过应用不同的网格计算,这四种平均温度之间的差异小于7.4%。计算得到的表面温度和换热对流系数与COMSOL数值结果和前人的研究结果相吻合。结果表明,在第二种情况下,计算温度降低。当水雾系统接近钢包层时,水雾系统能够更有效地冷却钢壁。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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