Conducting Polyanethole /Metals Oxides Nanocomposites for Corrosion Protection and Bioactivity

IF 1.2 Q3 MULTIDISCIPLINARY SCIENCES Baghdad Science Journal Pub Date : 2023-09-20 DOI:10.21123/bsj.2023.8458
Ayat Monther Alqudsi, Khulood Abid Saleh
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Abstract

Corrosion is critical to a researcher since it has a substantial impact on both people's safety and the economy. A new approach based on a unique material has been employed to prevent rusting. Conducting polymer-composites are material types that show promise for anticorrosion by electrochemical synthesis of polyanethole(PA)/metals oxide nanocomposite (ZnO,TiO2) on Stainless Steel 304L (SS-304L) which plays as working electrode by using electropolymerization technique. The synthesized coating polymer was characterized by Fourier transform-infrared spectroscopy (FTIR) and atomic force microscopy (AFM) checkups. The findings demonstrated that when compared to the blank SS- 304L, PA/Nano composite and PA provide the strongest corrosion defenses for the metal. The results explained that the corrosion protection increased from 71% for PA film to 98% for PA/ZnO film and to 87% for PA/TiO2 at 298K .In addition, calculations were made for the kinetic and thermodynamic parameters (Ea, A, ∆H, ∆S and ∆G). Escherichia coli and Staphylococcus aureus, two gram-positive and gram-negative bacteria, were used to test the biological activity of polymeric film (E.Coli).
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导电聚茴香醚/金属氧化物纳米复合材料的防腐和生物活性研究
腐蚀对研究人员来说是至关重要的,因为它对人们的安全和经济都有重大影响。采用了一种基于独特材料的新方法来防止生锈。导电聚合物复合材料是利用电聚合技术在不锈钢304L (SS-304L)作为工作电极上电化学合成聚甲醚(PA)/金属氧化物纳米复合材料(ZnO,TiO2)的一种具有防腐前景的材料类型。采用傅里叶变换红外光谱(FTIR)和原子力显微镜(AFM)对合成的涂层聚合物进行了表征。结果表明,与空白的SS- 304L相比,PA/Nano复合材料和PA对金属具有最强的防腐蚀能力。结果表明,在298K下,PA膜的防腐蚀性能从71%提高到98%,PA/ZnO膜的防腐蚀性能提高到87%,并对动力学和热力学参数(Ea, A,∆H,∆S和∆G)进行了计算。采用革兰氏阳性菌和革兰氏阴性菌大肠杆菌和金黄色葡萄球菌对聚合物膜(大肠杆菌)进行生物活性测定。
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来源期刊
Baghdad Science Journal
Baghdad Science Journal MULTIDISCIPLINARY SCIENCES-
CiteScore
2.00
自引率
50.00%
发文量
102
审稿时长
24 weeks
期刊介绍: The journal publishes academic and applied papers dealing with recent topics and scientific concepts. Papers considered for publication in biology, chemistry, computer sciences, physics, and mathematics. Accepted papers will be freely downloaded by professors, researchers, instructors, students, and interested workers. ( Open Access) Published Papers are registered and indexed in the universal libraries.
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