Simultaneous effect of welding current with post-weld T6 heat-treatment on corrosion susceptibility of Al6013 alloy joined by GTAW

Mehmet TOPUZ
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Abstract

Al6013 base metals were joined successfully with ER4047 weld metal by using the GTAW method under different welding currents. Post-weld T6 heat treatment effects on corrosion properties were investigated in terms of open circuit potential (OCP), potentiodynamic polarization (PDS), and electrochemical impedance spectroscopy (EIS) tests. It was determined that corrosion resistance of the post-weld samples increased with increasing welding current, while T6 heat-treatment only effective on 110A and 140A welding current samples (3.61 to 2.08, 2.95 to 2.40, and 1.38 to 2.15 µA·cm-2 for 110, 140, and 170A welding current before and after T6 heat-treatment). The characteristics of the oxide films on the surfaces are revealed with EIS analysis by a two-constant equivalent circuit model which observed that while the passive film originating from Al is formed on the surfaces, on the other hand, it contains a pittings on the surface. It was determined that the pitting resistance of the T6 heat-treated 110A samples increased (3075 to 4562 Ω). Post-corrosion SEM surface morphologies showed that low welding currents lead to more damage with increased exposure to corrosion.
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焊接电流与焊后T6热处理对GTAW连接Al6013合金腐蚀敏感性的影响
在不同的焊接电流下,采用GTAW方法成功地将Al6013母材与ER4047焊缝金属进行了焊接。通过开路电位(OCP)、动电位极化(PDS)和电化学阻抗谱(EIS)测试,研究焊后T6热处理对腐蚀性能的影响。结果表明,焊后试样的耐蚀性随焊接电流的增大而增大,而T6热处理仅对焊接电流为110A和140A的试样有效(T6热处理前后110、140、170A焊接电流分别为3.61 ~ 2.08、2.95 ~ 2.40、1.38 ~ 2.15µA·cm-2)。利用双常数等效电路模型,利用EIS分析揭示了表面氧化膜的特征,观察到在表面形成源自Al的钝化膜的同时,其表面也含有点蚀。经T6热处理的110A试样的抗点蚀性能提高(3075 ~ 4562 Ω)。腐蚀后的SEM表面形貌表明,随着腐蚀暴露的增加,低焊接电流导致更多的损伤。
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