Sustainable ultra-strong thermally conductive wood-based antibacterial structural materials with anti-corrosion and ultraviolet shielding

IF 10.7 Q1 CHEMISTRY, PHYSICAL EcoMat Pub Date : 2023-10-10 DOI:10.1002/eom2.12420
Haoran Ye, Yang Shi, Ben Bin Xu, Zhanhu Guo, Wei Fan, Zhongfeng Zhang, Daniel M. Mulvihill, Xuehua Zhang, Pengju Shi, Ximin He, Shengbo Ge
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Abstract

In light of the uprising global development on sustainability, an innovative and environmental friendly wood-based material derived from natural pinewood has been developed as a high-performance alternative to petrochemical-based materials. The wood-based functional material, named as BC-CaCl2, is synthesized through the coordination of carboxyl groups (−COOH) present in pinewood with calcium ions (Ca2+), which facilitates the formation of a high-density cross-linking structure through the combined action of intermolecular hydrogen bonds. The as-prepared BC-CaCl2 exhibits excellent tensile strength (470.5 MPa) and flexural strength (539.5 MPa), establishing a robust structural basis for the materials. Meanwhile, BC-CaCl2 shows good water resistance, thermal conductivity, thermal stability, UV resistance, corrosion resistance, and antibacterial properties. BC-CaCl2 represents a viable alternative to petrochemical-based materials. Its potential application areas include waterproof enclosure structure of buildings, indoor underfloor heating, outdoor UV resistant protective cover, and anti-corrosion materials for installation engineering, and so forth.

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具有防腐和紫外线屏蔽功能的可持续超强导热木基抗菌结构材料
随着全球对可持续发展的重视,一种从天然松木中提取的创新型环保木基材料应运而生,成为石化基材料的高性能替代品。这种木基功能材料被命名为 BC-CaCl2,是通过松木中的羧基(-COOH)与钙离子(Ca2+)配位合成的,通过分子间氢键的共同作用,促进了高密度交联结构的形成。制备的 BC-CaCl2 具有优异的拉伸强度(470.5 兆帕)和弯曲强度(539.5 兆帕),为材料奠定了坚实的结构基础。同时,BC-CaCl2 还具有良好的耐水性、导热性、热稳定性、抗紫外线性、耐腐蚀性和抗菌性。BC-CaCl2 是石油化工材料的可行替代品。其潜在的应用领域包括建筑物的防水围护结构、室内地板采暖、室外抗紫外线保护罩以及安装工程的防腐蚀材料等。
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审稿时长
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