Characterization of Activated Carbon and Application of Copper Removal from Drinking Water

Yasemen Kutmen Kalpakli, İkbal Koyuncu
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Abstract

In this study, removal of copper ions from aqueous solution by adsorption was investigated. The methods were applied to removal of copper in artificial water and drinking water samples using activated carbon. For this purpose, metal removal from water depends on the pH, initial concentration of metal, amount of activated carbon, and effect of sorption time were investigated. The process parameters were investigated with batch studies. In this study, commercial activated carbon, Chemviron C-1300, has been used. Granular activated carbon were characterized using nitrogen porosimetry, pH titration, Boehm's titration, mercury porosimetry, FTIR and scanning electron microscope measurements. The copper ions were determined by an atomic absorption spectrometry. Optimum conditions were found as concentration of 10 mg l-1, pH: 5, contact time:25 min, and activated carbon amount:750 mg. Optimum condition were applied to drinking water for removal of Cu(II). Furthermore, adsorption isotherm data were fitted to both Langmuir and Freundlich models for finding the optimum conditions.

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活性炭的表征及其在饮用水除铜中的应用
研究了吸附法去除水溶液中的铜离子。将该方法应用于活性炭去除人工水和饮用水样品中的铜。为此,考察了水中金属的去除率取决于pH值、金属的初始浓度、活性炭的用量和吸附时间的影响。对工艺参数进行了批量研究。在本研究中,使用了商用活性炭Chemviron C-1300。采用氮孔隙度法、pH滴定法、Boehm滴定法、汞孔隙度法、FTIR和扫描电镜对颗粒活性炭进行了表征。用原子吸收光谱法测定铜离子。最佳工艺条件为:浓度为10 mg l-1, pH为5,接触时间为25 min,活性炭用量为750 mg。研究了饮用水中Cu(II)的最佳去除条件。此外,吸附等温线数据拟合Langmuir和Freundlich模型,以寻找最佳条件。
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