Flash-pyrolyzed coal char as a high-performance anode for sodium-ion batteries

Abstract

This work explores a novel approach for improving the sodium-ion battery performance of coal char using flash pyrolysis and an ether-based electrolyte. Coal char is an ultra-low cost hard carbon with promising application as an anode material in sodium-ion batteries. During flash pyrolysis, char is heated at 1000 °C/s in a drop-tube furnace to create a highly-irregular structure. The larger d-spacing and smaller closed micropore diameter of flash-pyrolyzed char increases anode capacity compared to traditional slow-pyrolyzed char electrodes. The sodium-ion battery anode performance of flash-pyrolyzed char is further improved using an ether-based electrolyte in place of the traditional ester-based electrolyte. Performance improvements include greater initial Coulombic efficiency (58% in ester- vs. 64% in ether-based electrolyte) and improved specific capacity in an ether-based electrolyte. Overall, the combination of flash pyrolysis and ether-based electrolyte increases the sodium-ion battery discharge capacity of coal char by over 50%, from 72.5 mAh g⁻¹ (slow-pyrolyzed char in ester-based electrolyte) to 109.4 mAh g⁻¹ (flash-pyrolyzed char in ether-based electrolyte) (50 mA g⁻¹ discharge rate). The results highlight improvements that can be realized through flash pyrolysis of coal char for battery applications and the numerous processing advantages of flash vs. slow pyrolysis.