Study of the Slow Pyrolysis of Lignin, Hemicellulose, and Cellulose and the Effect of Their Interaction in Plant Biomass

IF 0.8 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY Solid Fuel Chemistry Pub Date : 2023-11-24 DOI:10.3103/S0361521923060083
V. M. Zaichenko, V. A. Lavrenov, Yu. M. Faleeva
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Abstract

The pyrolysis of two types of raw materials of plant origin (sawdust and sunflower husks), components of the organic matter of biomass (hemicellulose, cellulose, and lignin), and model mixtures prepared from components in accordance with their fractions in the raw materials was studied. Pyrolysis of the materials was carried out using TGA and a laboratory setup with a fixed bed reactor. The distribution and composition of the products were determined at pyrolysis temperatures of 350, 425, 500, and 575°C. Experimental data obtained with the biomass samples and model mixtures were compared with calculated values obtained based on the pyrolysis of individual components and their fractions in the biomass. The possibility of predicting the distribution of pyrolysis products depending on the component composition was investigated. The influence of intercomponent interaction in biomass on the yield and composition of pyrolysis products was revealed.

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木质素、半纤维素和纤维素在植物生物质中的缓慢热解及其相互作用的研究
研究了两种植物源原料(木屑和葵花籽壳)、生物质有机质组分(半纤维素、纤维素和木质素)以及组分在原料中按其馏分制备的模型混合物的热解过程。采用热重分析仪和固定床反应器对物料进行热解。在350、425、500和575℃热解温度下测定产物的分布和组成。将生物质样品和模型混合物的实验数据与基于生物质中单个组分及其馏分的热解计算值进行比较。探讨了根据组分组成预测热解产物分布的可能性。揭示了生物质组分间相互作用对热解产物产率和组成的影响。
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来源期刊
Solid Fuel Chemistry
Solid Fuel Chemistry CHEMISTRY, MULTIDISCIPLINARY-ENERGY & FUELS
CiteScore
1.10
自引率
28.60%
发文量
52
审稿时长
6-12 weeks
期刊介绍: The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.
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